Ru 4(CO) 8(μ-OOCAd) 4(PPh 3) 2: Phosphine derivative of an electron-deficient linear tetraruthenium cluster

Suat Ping Oh; Bo Yang Chor; Wai Yip Fan; Yongxin Li; Weng Kee Leong

doi:10.1021/om2009028

Ru ₄(CO) ₈(μ-OOCAd) ₄(PPh ₃) ₂: Phosphine derivative of an electron-deficient linear tetraruthenium cluster

Suat Ping Oh, Bo Yang Chor, Wai Yip Fan^*, Yongxin Li, Weng Kee Leong

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

The reaction of Ru ₃(CO) ₁₂ with 1-adamantanecarboxylic acid afforded a purple solid with the formulation Ru ₂(CO) ₄(μ-OOCAd) ₂ (Ad = 1-adamantyl). Reaction of this solid with PPh ₃ gave Ru ₄(CO) ₈(μ-OOCAd) ₄(PPh ₃) ₂, a 64-electron linear tetraruthenium cluster.

Original language	English
Pages (from-to)	6774-6777
Number of pages	4
Journal	Organometallics
Volume	30
Issue number	24
DOIs	https://doi.org/10.1021/om2009028
Publication status	Published - Dec 26 2011
Externally published	Yes

ASJC Scopus Subject Areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "Ru 4(CO) 8(μ-OOCAd) 4(PPh 3) 2: Phosphine derivative of an electron-deficient linear tetraruthenium cluster",

abstract = "The reaction of Ru 3(CO) 12 with 1-adamantanecarboxylic acid afforded a purple solid with the formulation Ru 2(CO) 4(μ-OOCAd) 2 (Ad = 1-adamantyl). Reaction of this solid with PPh 3 gave Ru 4(CO) 8(μ-OOCAd) 4(PPh 3) 2, a 64-electron linear tetraruthenium cluster.",

author = "Oh, {Suat Ping} and Chor, {Bo Yang} and Fan, {Wai Yip} and Yongxin Li and Leong, {Weng Kee}",

year = "2011",

month = dec,

day = "26",

doi = "10.1021/om2009028",

language = "English",

volume = "30",

pages = "6774--6777",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "24",

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TY - JOUR

T1 - Ru 4(CO) 8(μ-OOCAd) 4(PPh 3) 2

T2 - Phosphine derivative of an electron-deficient linear tetraruthenium cluster

AU - Oh, Suat Ping

AU - Chor, Bo Yang

AU - Fan, Wai Yip

AU - Li, Yongxin

AU - Leong, Weng Kee

PY - 2011/12/26

Y1 - 2011/12/26

N2 - The reaction of Ru 3(CO) 12 with 1-adamantanecarboxylic acid afforded a purple solid with the formulation Ru 2(CO) 4(μ-OOCAd) 2 (Ad = 1-adamantyl). Reaction of this solid with PPh 3 gave Ru 4(CO) 8(μ-OOCAd) 4(PPh 3) 2, a 64-electron linear tetraruthenium cluster.

AB - The reaction of Ru 3(CO) 12 with 1-adamantanecarboxylic acid afforded a purple solid with the formulation Ru 2(CO) 4(μ-OOCAd) 2 (Ad = 1-adamantyl). Reaction of this solid with PPh 3 gave Ru 4(CO) 8(μ-OOCAd) 4(PPh 3) 2, a 64-electron linear tetraruthenium cluster.

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UR - http://www.scopus.com/inward/citedby.url?scp=84055213585&partnerID=8YFLogxK

U2 - 10.1021/om2009028

DO - 10.1021/om2009028

M3 - Article

AN - SCOPUS:84055213585

SN - 0276-7333

VL - 30

SP - 6774

EP - 6777

JO - Organometallics

JF - Organometallics

IS - 24

ER -

Ru ₄(CO) ₈(μ-OOCAd) ₄(PPh ₃) ₂: Phosphine derivative of an electron-deficient linear tetraruthenium cluster

Abstract

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