Self-assembly of a hydrogen-bonded association chain liquid crystalline polymer (LCP)

Xuehong Lu, Chaobin He*, Clemon D. Terrell, Anselm C. Griffin

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

14 Citations (Scopus)

Abstract

A hydrogen-bonded association chain liquid crystalline polymer (LCP) based on tetraethyleneglycoxybis(2,6-dimethyl-4-benzoic acid) and 4,4′-(p-phenylenedi-1,2-ethenediyl)bipyridyl in a 1:1 stoichiometric ratio was synthesized using melting mixing method. X-ray scattering from fiber drawn from its nematic phase exhibits preferred orientation, indicating that hydrogen bonding association chain polymer can also be strong enough to withstand the shear or tensile force and could be macroscopically oriented under shear or tensile force. Two complimentary components are likely to form a co-crystallized structure to form a monoclinic crystal.

Original languageEnglish
Pages (from-to)85-88
Number of pages4
JournalMacromolecular Chemistry and Physics
Volume203
Issue number1
DOIs
Publication statusPublished - Jan 9 2002
Externally publishedYes

ASJC Scopus Subject Areas

  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Polymers and Plastics
  • Organic Chemistry
  • Materials Chemistry

Keywords

  • Hydrogen-bonded
  • Liquid-crystalline polymers (LCP)
  • Self-assembly
  • Structure

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