Silicon as a directing group in the phosphine-catalyzed [2 + 3]-cycloaddition of aryl allenones with electron-deficient olefins

Magesh Sampath; Teck Peng Loh

doi:10.1039/b819959k

Silicon as a directing group in the phosphine-catalyzed [2 + 3]-cycloaddition of aryl allenones with electron-deficient olefins

Magesh Sampath, Teck Peng Loh^*

^*Corresponding author for this work

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

72 Citations (Scopus)

Abstract

This Communication describes a highly efficient phosphine-catalyzed [2 + 3]-cycloaddition reaction using α-trimethylsilyl-substituted aryl allenones and electron deficient olefins; both good yields and good asymmetric induction were obtained.

Original language	English
Pages (from-to)	1568-1570
Number of pages	3
Journal	Chemical Communications
Issue number	12
DOIs	https://doi.org/10.1039/b819959k
Publication status	Published - 2009
Externally published	Yes

ASJC Scopus Subject Areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Silicon as a directing group in the phosphine-catalyzed [2 + 3]-cycloaddition of aryl allenones with electron-deficient olefins",

abstract = "This Communication describes a highly efficient phosphine-catalyzed [2 + 3]-cycloaddition reaction using α-trimethylsilyl-substituted aryl allenones and electron deficient olefins; both good yields and good asymmetric induction were obtained.",

author = "Magesh Sampath and Loh, {Teck Peng}",

year = "2009",

doi = "10.1039/b819959k",

language = "English",

pages = "1568--1570",

journal = "Chemical Communications",

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AU - Sampath, Magesh

AU - Loh, Teck Peng

PY - 2009

Y1 - 2009

N2 - This Communication describes a highly efficient phosphine-catalyzed [2 + 3]-cycloaddition reaction using α-trimethylsilyl-substituted aryl allenones and electron deficient olefins; both good yields and good asymmetric induction were obtained.

AB - This Communication describes a highly efficient phosphine-catalyzed [2 + 3]-cycloaddition reaction using α-trimethylsilyl-substituted aryl allenones and electron deficient olefins; both good yields and good asymmetric induction were obtained.

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JO - Chemical Communications

JF - Chemical Communications

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Silicon as a directing group in the phosphine-catalyzed [2 + 3]-cycloaddition of aryl allenones with electron-deficient olefins

Abstract

ASJC Scopus Subject Areas

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