Stereoselective hydrosilylation of terminal alkynes catalyzed by [Cp*IrCl2]2: A computational and experimental study

Venugopal Shanmugham Sridevi; Yip Fan Wai; Kee Leong Weng

doi:10.1021/om0609158

Stereoselective hydrosilylation of terminal alkynes catalyzed by [Cp*IrCl₂]₂: A computational and experimental study

Venugopal Shanmugham Sridevi, Yip Fan Wai, Kee Leong Weng^*

^*Corresponding author for this work

National University of Singapore

Research output: Contribution to journal › Article › peer-review

55 Citations (Scopus)

Abstract

The hydrosilylation of terminal alkynes is catalyzed by [Cp*IrCl ₂]₂ to afford selectively the β-(Z)-vinylsilanes in high yields. A catalytic cycle based on an Ir(III)-Ir(V) redox process is proposed.

Original language	English
Pages (from-to)	1157-1160
Number of pages	4
Journal	Organometallics
Volume	26
Issue number	5
DOIs	https://doi.org/10.1021/om0609158
Publication status	Published - Feb 26 2007
Externally published	Yes

ASJC Scopus Subject Areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "Stereoselective hydrosilylation of terminal alkynes catalyzed by [Cp*IrCl2]2: A computational and experimental study",

abstract = "The hydrosilylation of terminal alkynes is catalyzed by [Cp*IrCl 2]2 to afford selectively the β-(Z)-vinylsilanes in high yields. A catalytic cycle based on an Ir(III)-Ir(V) redox process is proposed.",

author = "Sridevi, {Venugopal Shanmugham} and Wai, {Yip Fan} and Weng, {Kee Leong}",

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AU - Weng, Kee Leong

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N2 - The hydrosilylation of terminal alkynes is catalyzed by [Cp*IrCl 2]2 to afford selectively the β-(Z)-vinylsilanes in high yields. A catalytic cycle based on an Ir(III)-Ir(V) redox process is proposed.

AB - The hydrosilylation of terminal alkynes is catalyzed by [Cp*IrCl 2]2 to afford selectively the β-(Z)-vinylsilanes in high yields. A catalytic cycle based on an Ir(III)-Ir(V) redox process is proposed.

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Stereoselective hydrosilylation of terminal alkynes catalyzed by [Cp*IrCl₂]₂: A computational and experimental study

Abstract

ASJC Scopus Subject Areas

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