Structural Mimics of the [Fe]-Hydrogenase: A Complete Set for Group VIII Metals

Chandan Kr Barik; Rakesh Ganguly; Yongxin Li; Weng Kee Leong

doi:10.1021/acs.inorgchem.8b00838

Structural Mimics of the [Fe]-Hydrogenase: A Complete Set for Group VIII Metals

Chandan Kr Barik, Rakesh Ganguly, Yongxin Li, Weng Kee Leong^*

^*Corresponding author for this work

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

A set of structural mimics of the [Fe]-hydrogenase active site comprising all the group VIII metals, viz., [M(2-NHC(O)C₅H₄N)(CO)₂(2-S-C₅H₄N)], has been synthesized. They exist as a mixture of isomers in solution, and the relative stability of the isomers depends on the nature of the metal and the substituent at the 6-position of the pyridine ligand.

Original language	English
Pages (from-to)	7113-7120
Number of pages	8
Journal	Inorganic Chemistry
Volume	57
Issue number	12
DOIs	https://doi.org/10.1021/acs.inorgchem.8b00838
Publication status	Published - Jun 18 2018
Externally published	Yes

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Publisher Copyright:
© 2018 American Chemical Society.

ASJC Scopus Subject Areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/acs.inorgchem.8b00838

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AB - A set of structural mimics of the [Fe]-hydrogenase active site comprising all the group VIII metals, viz., [M(2-NHC(O)C5H4N)(CO)2(2-S-C5H4N)], has been synthesized. They exist as a mixture of isomers in solution, and the relative stability of the isomers depends on the nature of the metal and the substituent at the 6-position of the pyridine ligand.

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Structural Mimics of the [Fe]-Hydrogenase: A Complete Set for Group VIII Metals

Abstract

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ASJC Scopus Subject Areas

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