Studies towards total synthesis of antillatoxin: Investigation of the indium-mediated allylation reactions of carbonyl compounds with β-bromocrotylbromide in water

Teck Peng Loh; Guo Qiang Cao; Jian Pei

doi:10.1016/S0040-4039(97)10826-7

Studies towards total synthesis of antillatoxin: Investigation of the indium-mediated allylation reactions of carbonyl compounds with β-bromocrotylbromide in water

Teck Peng Loh^*, Guo Qiang Cao, Jian Pei

^*Corresponding author for this work

National University of Singapore

Research output: Contribution to journal › Article › peer-review

64 Citations (Scopus)

Abstract

Indium mediates the coupling of β-bromocrotylbromide with carbonyl compounds in saturated ammonium chloride in the presence of lanthanide triflate under sonication to give the corresponding compounds in good yield and moderate to high syn diastereoselectivity.

Original language	English
Pages (from-to)	1453-1456
Number of pages	4
Journal	Tetrahedron Letters
Volume	39
Issue number	11
DOIs	https://doi.org/10.1016/S0040-4039(97)10826-7
Publication status	Published - Mar 12 1998
Externally published	Yes

ASJC Scopus Subject Areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(97)10826-7

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title = "Studies towards total synthesis of antillatoxin: Investigation of the indium-mediated allylation reactions of carbonyl compounds with β-bromocrotylbromide in water",

abstract = "Indium mediates the coupling of β-bromocrotylbromide with carbonyl compounds in saturated ammonium chloride in the presence of lanthanide triflate under sonication to give the corresponding compounds in good yield and moderate to high syn diastereoselectivity.",

author = "Loh, {Teck Peng} and Cao, {Guo Qiang} and Jian Pei",

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AU - Cao, Guo Qiang

AU - Pei, Jian

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Studies towards total synthesis of antillatoxin: Investigation of the indium-mediated allylation reactions of carbonyl compounds with β-bromocrotylbromide in water

Abstract

ASJC Scopus Subject Areas

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