Substitution derivatives of the heteronuclear cluster RuOs3(μ-H)2(CO)13: Monosubstituted group 15 derivatives

Leonard Joachim Pereira; Weng Kee Leong

doi:10.1016/j.jorganchem.2006.01.028

Substitution derivatives of the heteronuclear cluster RuOs₃(μ-H)₂(CO)₁₃: Monosubstituted group 15 derivatives

Leonard Joachim Pereira, Weng Kee Leong^*

^*Corresponding author for this work

National University of Singapore

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

Tertiary group 15 ligand monosubstituted derivatives of the heteronuclear cluster RuOs₃(μ-H)₂(CO)₁₃ have been prepared and their solid state and solution structures examined. A number of isomeric structural types have been identified in solution, and these appear to be correlated to disorder in the solid state. Hydride fluxionality and restricted rotation about the metal-phosphorus bond have also been observed.

Original language	English
Pages (from-to)	2448-2456
Number of pages	9
Journal	Journal of Organometallic Chemistry
Volume	691
Issue number	11
DOIs	https://doi.org/10.1016/j.jorganchem.2006.01.028
Publication status	Published - May 15 2006
Externally published	Yes

ASJC Scopus Subject Areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Keywords

Heterometallic complexes
Osmium
Phosphanes
Ruthenium

Access to Document

10.1016/j.jorganchem.2006.01.028

Cite this

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abstract = "Tertiary group 15 ligand monosubstituted derivatives of the heteronuclear cluster RuOs3(μ-H)2(CO)13 have been prepared and their solid state and solution structures examined. A number of isomeric structural types have been identified in solution, and these appear to be correlated to disorder in the solid state. Hydride fluxionality and restricted rotation about the metal-phosphorus bond have also been observed.",

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AU - Leong, Weng Kee

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AB - Tertiary group 15 ligand monosubstituted derivatives of the heteronuclear cluster RuOs3(μ-H)2(CO)13 have been prepared and their solid state and solution structures examined. A number of isomeric structural types have been identified in solution, and these appear to be correlated to disorder in the solid state. Hydride fluxionality and restricted rotation about the metal-phosphorus bond have also been observed.

KW - Heterometallic complexes

KW - Osmium

KW - Phosphanes

KW - Ruthenium

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