Surface-initiated living radical polymerizations using iodine, organotellurium, and organic catalysts

Atsushi Goto; Yoshinobu Tsujii

doi:10.1007/12_2015_310

Surface-initiated living radical polymerizations using iodine, organotellurium, and organic catalysts

Atsushi Goto^*, Yoshinobu Tsujii

^*Corresponding author for this work

Kyoto University

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

This chapter reviews surface-initiated living radical polymerizations via iodine transfer polymerization (ITP), organotellurium-mediated radical polymerization (TERP), and reversible chain-transfer catalyzed polymerization (RTCP) using organic catalysts. The successful application of these polymerizations made it possible to graft various polymers with well-defined structures onto flat substrates and nanoparticles. Living radical polymerizations, including ITP, TERP, and RTCP, also lead to a striking increase in the graft density. Because of their unique advantages as synthetic tools, ITP, TERP, and RTCP can be used to expand the scope of controlled surface modification.

Original language	English
Pages (from-to)	107-122
Number of pages	16
Journal	Advances in Polymer Science
Volume	270
DOIs	https://doi.org/10.1007/12_2015_310
Publication status	Published - 2016
Externally published	Yes

Bibliographical note

Publisher Copyright:
© Springer International Publishing Switzerland 2015.

ASJC Scopus Subject Areas

General Chemical Engineering
Organic Chemistry
Polymers and Plastics

Keywords

Iodine
Living radical polymerization
Organic catalyst
Organotellurium
Polymer brush
Surfaceinitiated

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10.1007/12_2015_310

Cite this

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title = "Surface-initiated living radical polymerizations using iodine, organotellurium, and organic catalysts",

abstract = "This chapter reviews surface-initiated living radical polymerizations via iodine transfer polymerization (ITP), organotellurium-mediated radical polymerization (TERP), and reversible chain-transfer catalyzed polymerization (RTCP) using organic catalysts. The successful application of these polymerizations made it possible to graft various polymers with well-defined structures onto flat substrates and nanoparticles. Living radical polymerizations, including ITP, TERP, and RTCP, also lead to a striking increase in the graft density. Because of their unique advantages as synthetic tools, ITP, TERP, and RTCP can be used to expand the scope of controlled surface modification.",

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year = "2016",

doi = "10.1007/12_2015_310",

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journal = "Advances in Polymer Science",

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AU - Goto, Atsushi

AU - Tsujii, Yoshinobu

N1 - Publisher Copyright: © Springer International Publishing Switzerland 2015.

PY - 2016

Y1 - 2016

N2 - This chapter reviews surface-initiated living radical polymerizations via iodine transfer polymerization (ITP), organotellurium-mediated radical polymerization (TERP), and reversible chain-transfer catalyzed polymerization (RTCP) using organic catalysts. The successful application of these polymerizations made it possible to graft various polymers with well-defined structures onto flat substrates and nanoparticles. Living radical polymerizations, including ITP, TERP, and RTCP, also lead to a striking increase in the graft density. Because of their unique advantages as synthetic tools, ITP, TERP, and RTCP can be used to expand the scope of controlled surface modification.

AB - This chapter reviews surface-initiated living radical polymerizations via iodine transfer polymerization (ITP), organotellurium-mediated radical polymerization (TERP), and reversible chain-transfer catalyzed polymerization (RTCP) using organic catalysts. The successful application of these polymerizations made it possible to graft various polymers with well-defined structures onto flat substrates and nanoparticles. Living radical polymerizations, including ITP, TERP, and RTCP, also lead to a striking increase in the graft density. Because of their unique advantages as synthetic tools, ITP, TERP, and RTCP can be used to expand the scope of controlled surface modification.

KW - Iodine

KW - Living radical polymerization

KW - Organic catalyst

KW - Organotellurium

KW - Polymer brush

KW - Surfaceinitiated

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DO - 10.1007/12_2015_310

M3 - Article

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JO - Advances in Polymer Science

JF - Advances in Polymer Science

ER -

Surface-initiated living radical polymerizations using iodine, organotellurium, and organic catalysts

Abstract

Bibliographical note

ASJC Scopus Subject Areas

Keywords

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