Synergistic capacitive behavior between polyaniline and carbon black

Huanhuan Wang; Jilei Liu; Zhen Chen; Shi Chen; Tze Chien Sum; Jianyi Lin; Ze Xiang Shen

doi:10.1016/j.electacta.2017.01.164

Synergistic capacitive behavior between polyaniline and carbon black

Huanhuan Wang, Jilei Liu^*, Zhen Chen, Shi Chen, Tze Chien Sum, Jianyi Lin, Ze Xiang Shen

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

40 Citations (Scopus)

Abstract

Polyaniline (PANi) is an excellent electrode material with high pseudocapacitance for supercapacitors. Here the binder-free supercapacitor electrodes with high specific capacitance (458 F g⁻¹ at 2 mV s⁻¹) and Coulombic efficiency (100%) are successfully synthesized via a one-step potentialdynamic co-deposition of PANi and carbon black (CB). Significant synergistic effect between PANi and CB is demonstrated. Particularly, CB as the secondary dopant of PANi has been found to play an important role in producing higher conductivity, extended conformation structure, improved porosity, higher oxidation state and depressed hydrolysis effect, leading to superior capacitive performance. This promotes better understanding about synergistic effect between active materials and carbon additives, and opens up new research direction for high performance electrode design.

Original language	English
Pages (from-to)	236-244
Number of pages	9
Journal	Electrochimica Acta
Volume	230
DOIs	https://doi.org/10.1016/j.electacta.2017.01.164
Publication status	Published - Mar 10 2017
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2017 Elsevier Ltd

ASJC Scopus Subject Areas

General Chemical Engineering
Electrochemistry

Keywords

CB
PANi
supercapacitor
Synergistic effect

Access to Document

10.1016/j.electacta.2017.01.164

Cite this

@article{fd4315f3f1374e7fa0d2b09b8d124505,

title = "Synergistic capacitive behavior between polyaniline and carbon black",

abstract = "Polyaniline (PANi) is an excellent electrode material with high pseudocapacitance for supercapacitors. Here the binder-free supercapacitor electrodes with high specific capacitance (458 F g−1 at 2 mV s−1) and Coulombic efficiency (100\%) are successfully synthesized via a one-step potentialdynamic co-deposition of PANi and carbon black (CB). Significant synergistic effect between PANi and CB is demonstrated. Particularly, CB as the secondary dopant of PANi has been found to play an important role in producing higher conductivity, extended conformation structure, improved porosity, higher oxidation state and depressed hydrolysis effect, leading to superior capacitive performance. This promotes better understanding about synergistic effect between active materials and carbon additives, and opens up new research direction for high performance electrode design.",

keywords = "CB, PANi, supercapacitor, Synergistic effect",

author = "Huanhuan Wang and Jilei Liu and Zhen Chen and Shi Chen and Sum, \{Tze Chien\} and Jianyi Lin and Shen, \{Ze Xiang\}",

note = "Publisher Copyright: {\textcopyright} 2017 Elsevier Ltd",

year = "2017",

month = mar,

day = "10",

doi = "10.1016/j.electacta.2017.01.164",

language = "English",

volume = "230",

pages = "236--244",

journal = "Electrochimica Acta",

issn = "0013-4686",

publisher = "Elsevier Limited",

}

TY - JOUR

T1 - Synergistic capacitive behavior between polyaniline and carbon black

AU - Wang, Huanhuan

AU - Liu, Jilei

AU - Chen, Zhen

AU - Chen, Shi

AU - Sum, Tze Chien

AU - Lin, Jianyi

AU - Shen, Ze Xiang

PY - 2017/3/10

Y1 - 2017/3/10

N2 - Polyaniline (PANi) is an excellent electrode material with high pseudocapacitance for supercapacitors. Here the binder-free supercapacitor electrodes with high specific capacitance (458 F g−1 at 2 mV s−1) and Coulombic efficiency (100%) are successfully synthesized via a one-step potentialdynamic co-deposition of PANi and carbon black (CB). Significant synergistic effect between PANi and CB is demonstrated. Particularly, CB as the secondary dopant of PANi has been found to play an important role in producing higher conductivity, extended conformation structure, improved porosity, higher oxidation state and depressed hydrolysis effect, leading to superior capacitive performance. This promotes better understanding about synergistic effect between active materials and carbon additives, and opens up new research direction for high performance electrode design.

AB - Polyaniline (PANi) is an excellent electrode material with high pseudocapacitance for supercapacitors. Here the binder-free supercapacitor electrodes with high specific capacitance (458 F g−1 at 2 mV s−1) and Coulombic efficiency (100%) are successfully synthesized via a one-step potentialdynamic co-deposition of PANi and carbon black (CB). Significant synergistic effect between PANi and CB is demonstrated. Particularly, CB as the secondary dopant of PANi has been found to play an important role in producing higher conductivity, extended conformation structure, improved porosity, higher oxidation state and depressed hydrolysis effect, leading to superior capacitive performance. This promotes better understanding about synergistic effect between active materials and carbon additives, and opens up new research direction for high performance electrode design.

KW - CB

KW - PANi

KW - supercapacitor

KW - Synergistic effect

UR - http://www.scopus.com/inward/record.url?scp=85012115878&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85012115878&partnerID=8YFLogxK

U2 - 10.1016/j.electacta.2017.01.164

DO - 10.1016/j.electacta.2017.01.164

M3 - Article

AN - SCOPUS:85012115878

SN - 0013-4686

VL - 230

SP - 236

EP - 244

JO - Electrochimica Acta

JF - Electrochimica Acta

ER -

Synergistic capacitive behavior between polyaniline and carbon black

Abstract

Bibliographical note

ASJC Scopus Subject Areas

Keywords

Access to Document

Other files and links

Fingerprint

Cite this