Syngas-mediated C-C bond formation in flow: Selective rhodium-catalysed hydroformylation of styrenes

Sivarajan Kasinathan; Samuel L. Bourne; Päivi Tolstoy; Peter Koos; Matthew Obrien; Roderick W. Bates; Ian R. Baxendale; Steven V. Ley

doi:10.1055/s-0031-1289292

Syngas-mediated C-C bond formation in flow: Selective rhodium-catalysed hydroformylation of styrenes

Sivarajan Kasinathan, Samuel L. Bourne, Päivi Tolstoy, Peter Koos, Matthew Obrien, Roderick W. Bates, Ian R. Baxendale, Steven V. Ley^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

65 Citations (Scopus)

Abstract

We report a continuous flow, rhodium-catalysed hydroformylation of various styrenes using a tube-in-tube gas-liquid reactor. The flow process afforded selectively branched aryl aldehydes in good yields.

Original language	English
Pages (from-to)	2648-2651
Number of pages	4
Journal	Synlett
Issue number	18
DOIs	https://doi.org/10.1055/s-0031-1289292
Publication status	Published - 2011
Externally published	Yes

ASJC Scopus Subject Areas

Organic Chemistry

Keywords

catalysis
flow
hydroformylation
membrane
rhodium

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abstract = "We report a continuous flow, rhodium-catalysed hydroformylation of various styrenes using a tube-in-tube gas-liquid reactor. The flow process afforded selectively branched aryl aldehydes in good yields.",

keywords = "catalysis, flow, hydroformylation, membrane, rhodium",

author = "Sivarajan Kasinathan and Bourne, {Samuel L.} and P{\"a}ivi Tolstoy and Peter Koos and Matthew Obrien and Bates, {Roderick W.} and Baxendale, {Ian R.} and Ley, {Steven V.}",

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T2 - Selective rhodium-catalysed hydroformylation of styrenes

AU - Kasinathan, Sivarajan

AU - Bourne, Samuel L.

AU - Tolstoy, Päivi

AU - Koos, Peter

AU - Obrien, Matthew

AU - Bates, Roderick W.

AU - Baxendale, Ian R.

AU - Ley, Steven V.

PY - 2011

Y1 - 2011

N2 - We report a continuous flow, rhodium-catalysed hydroformylation of various styrenes using a tube-in-tube gas-liquid reactor. The flow process afforded selectively branched aryl aldehydes in good yields.

AB - We report a continuous flow, rhodium-catalysed hydroformylation of various styrenes using a tube-in-tube gas-liquid reactor. The flow process afforded selectively branched aryl aldehydes in good yields.

KW - catalysis

KW - flow

KW - hydroformylation

KW - membrane

KW - rhodium

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Syngas-mediated C-C bond formation in flow: Selective rhodium-catalysed hydroformylation of styrenes

Abstract

ASJC Scopus Subject Areas

Keywords

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