TY - JOUR
T1 - Synthesis and X-ray structural characterisation of the phosphido-bridged triosmium carbonyl cluster [Os3(μ-H)(CO)10(μ-P(C6F5)H)]
T2 - cleavage of a PC bond of a secondary phosphine
AU - Ang, H. G.
AU - Kwik, W. L.
AU - Leong, W. K.
AU - Johnson, Brian F.G.
AU - Lewis, Jack
AU - Raithby, Paul R.
PY - 1990/10/16
Y1 - 1990/10/16
N2 - The reaction of the anion [Os3H(CO)11]- with bis(pentafluorophenyl)phosphine, (C6F5)2PH, results in the cleavage of a PC bond and the formation of the bridged phosphido cluster [Os3(μ-H)(CO)10(μ-P(C6F6)H)]. The structure of this product has been confirmed by a single-crystal X-ray diffraction study which shows that the P(C6F5)H ligand and the hydrido bridge the long edge (2.916(1) Å) of the isosceles osmium triangle.
AB - The reaction of the anion [Os3H(CO)11]- with bis(pentafluorophenyl)phosphine, (C6F5)2PH, results in the cleavage of a PC bond and the formation of the bridged phosphido cluster [Os3(μ-H)(CO)10(μ-P(C6F6)H)]. The structure of this product has been confirmed by a single-crystal X-ray diffraction study which shows that the P(C6F5)H ligand and the hydrido bridge the long edge (2.916(1) Å) of the isosceles osmium triangle.
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U2 - 10.1016/0022-328X(90)85483-F
DO - 10.1016/0022-328X(90)85483-F
M3 - Article
AN - SCOPUS:0038140432
SN - 0022-328X
VL - 396
SP - C43-C46
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 2-3
ER -