Synthesis, crystal structure, and optical properties of a three-dimensional quaternary Hg-In-S-Cl chalcohalide: Hg 7InS 6Cl 5

Yi Liu; Fengxia Wei; Sing Ning Yeo; Fu Min Lee; Christian Kloc; Qingyu Yan; Huey Hoon Hng; Jan Ma; Qichun Zhang

doi:10.1021/ic202746y

Synthesis, crystal structure, and optical properties of a three-dimensional quaternary Hg-In-S-Cl chalcohalide: Hg ₇InS ₆Cl ₅

Yi Liu, Fengxia Wei, Sing Ning Yeo, Fu Min Lee, Christian Kloc, Qingyu Yan, Huey Hoon Hng, Jan Ma, Qichun Zhang^*

^*Corresponding author for this work

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

40 Citations (Scopus)

Abstract

A crystalline three-dimensional (3D) quaternary chalcohalide, Hg ₇InS ₆Cl ₅ (1), has been synthesized through a solid-state reaction under medium temperature. It is the first example in the family of the Hg-IIIA-Q-X (Q = S, Se, Te; X = F, Cl, Br, I) systems. Compound 1 features a 3D network and has an optical band gap of 2.54 eV.

Original language	English
Pages (from-to)	4414-4416
Number of pages	3
Journal	Inorganic Chemistry
Volume	51
Issue number	8
DOIs	https://doi.org/10.1021/ic202746y
Publication status	Published - Apr 16 2012
Externally published	Yes

ASJC Scopus Subject Areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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title = "Synthesis, crystal structure, and optical properties of a three-dimensional quaternary Hg-In-S-Cl chalcohalide: Hg 7InS 6Cl 5",

abstract = "A crystalline three-dimensional (3D) quaternary chalcohalide, Hg 7InS 6Cl 5 (1), has been synthesized through a solid-state reaction under medium temperature. It is the first example in the family of the Hg-IIIA-Q-X (Q = S, Se, Te; X = F, Cl, Br, I) systems. Compound 1 features a 3D network and has an optical band gap of 2.54 eV.",

author = "Yi Liu and Fengxia Wei and Yeo, \{Sing Ning\} and Lee, \{Fu Min\} and Christian Kloc and Qingyu Yan and Hng, \{Huey Hoon\} and Jan Ma and Qichun Zhang",

year = "2012",

month = apr,

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doi = "10.1021/ic202746y",

language = "English",

volume = "51",

pages = "4414--4416",

journal = "Inorganic Chemistry",

issn = "0020-1669",

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T1 - Synthesis, crystal structure, and optical properties of a three-dimensional quaternary Hg-In-S-Cl chalcohalide

T2 - Hg 7InS 6Cl 5

AU - Liu, Yi

AU - Wei, Fengxia

AU - Yeo, Sing Ning

AU - Lee, Fu Min

AU - Kloc, Christian

AU - Yan, Qingyu

AU - Hng, Huey Hoon

AU - Ma, Jan

AU - Zhang, Qichun

PY - 2012/4/16

Y1 - 2012/4/16

N2 - A crystalline three-dimensional (3D) quaternary chalcohalide, Hg 7InS 6Cl 5 (1), has been synthesized through a solid-state reaction under medium temperature. It is the first example in the family of the Hg-IIIA-Q-X (Q = S, Se, Te; X = F, Cl, Br, I) systems. Compound 1 features a 3D network and has an optical band gap of 2.54 eV.

AB - A crystalline three-dimensional (3D) quaternary chalcohalide, Hg 7InS 6Cl 5 (1), has been synthesized through a solid-state reaction under medium temperature. It is the first example in the family of the Hg-IIIA-Q-X (Q = S, Se, Te; X = F, Cl, Br, I) systems. Compound 1 features a 3D network and has an optical band gap of 2.54 eV.

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DO - 10.1021/ic202746y

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 8

ER -

Synthesis, crystal structure, and optical properties of a three-dimensional quaternary Hg-In-S-Cl chalcohalide: Hg ₇InS ₆Cl ₅

Abstract

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