Synthesis of Block Copolymers by Mechanistic Transformation from Reversible Complexation Mediated Living Radical Polymerization to the Photoinduced Radical Oxidation/Addition/Deactivation Process

Cansu Aydogan; F. Simal Aykac; Gorkem Yilmaz; Ye Qiu Chew; Atsushi Goto; Yusuf Yagci

doi:10.1021/acsmacrolett.2c00004

Synthesis of Block Copolymers by Mechanistic Transformation from Reversible Complexation Mediated Living Radical Polymerization to the Photoinduced Radical Oxidation/Addition/Deactivation Process

Cansu Aydogan, F. Simal Aykac, Gorkem Yilmaz, Ye Qiu Chew, Atsushi Goto^*, Yusuf Yagci^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

A versatile strategy for the fabrication of block copolymers by the combination of two discrete living polymerization techniques-reversible complexation mediated living radical polymerization (RCMP) and photoinduced radical oxidation addition deactivation (PROAD) processes-is reported. First, RCMP is conducted to yield poly(methyl methacrylate) with iodide end groups (PMMA-I). In the following step, PMMA-I is used as macroinitiator for living PROAD cationic polymerization of isobutyl vinyl ether. Successful formation of the block copolymers is confirmed by ¹H NMR, FT-IR, GPC, and DSC investigations.

Original language	English
Pages (from-to)	342-346
Number of pages	5
Journal	ACS Macro Letters
Volume	11
Issue number	3
DOIs	https://doi.org/10.1021/acsmacrolett.2c00004
Publication status	Published - Mar 15 2022
Externally published	Yes

Bibliographical note

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© 2022 American Chemical Society. All rights reserved.

ASJC Scopus Subject Areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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10.1021/acsmacrolett.2c00004

Cite this

@article{568cba37efda4759958ce13dcc1fbfd1,

title = "Synthesis of Block Copolymers by Mechanistic Transformation from Reversible Complexation Mediated Living Radical Polymerization to the Photoinduced Radical Oxidation/Addition/Deactivation Process",

abstract = "A versatile strategy for the fabrication of block copolymers by the combination of two discrete living polymerization techniques-reversible complexation mediated living radical polymerization (RCMP) and photoinduced radical oxidation addition deactivation (PROAD) processes-is reported. First, RCMP is conducted to yield poly(methyl methacrylate) with iodide end groups (PMMA-I). In the following step, PMMA-I is used as macroinitiator for living PROAD cationic polymerization of isobutyl vinyl ether. Successful formation of the block copolymers is confirmed by 1H NMR, FT-IR, GPC, and DSC investigations.",

author = "Cansu Aydogan and Aykac, {F. Simal} and Gorkem Yilmaz and Chew, {Ye Qiu} and Atsushi Goto and Yusuf Yagci",

year = "2022",

month = mar,

day = "15",

doi = "10.1021/acsmacrolett.2c00004",

language = "English",

volume = "11",

pages = "342--346",

journal = "ACS Macro Letters",

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publisher = "American Chemical Society",

number = "3",

}

Synthesis of Block Copolymers by Mechanistic Transformation from Reversible Complexation Mediated Living Radical Polymerization to the Photoinduced Radical Oxidation/Addition/Deactivation Process. / Aydogan, Cansu; Aykac, F. Simal; Yilmaz, Gorkem et al.
In: ACS Macro Letters, Vol. 11, No. 3, 15.03.2022, p. 342-346.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis of Block Copolymers by Mechanistic Transformation from Reversible Complexation Mediated Living Radical Polymerization to the Photoinduced Radical Oxidation/Addition/Deactivation Process

AU - Aydogan, Cansu

AU - Aykac, F. Simal

AU - Yilmaz, Gorkem

AU - Chew, Ye Qiu

AU - Goto, Atsushi

AU - Yagci, Yusuf

PY - 2022/3/15

Y1 - 2022/3/15

N2 - A versatile strategy for the fabrication of block copolymers by the combination of two discrete living polymerization techniques-reversible complexation mediated living radical polymerization (RCMP) and photoinduced radical oxidation addition deactivation (PROAD) processes-is reported. First, RCMP is conducted to yield poly(methyl methacrylate) with iodide end groups (PMMA-I). In the following step, PMMA-I is used as macroinitiator for living PROAD cationic polymerization of isobutyl vinyl ether. Successful formation of the block copolymers is confirmed by 1H NMR, FT-IR, GPC, and DSC investigations.

AB - A versatile strategy for the fabrication of block copolymers by the combination of two discrete living polymerization techniques-reversible complexation mediated living radical polymerization (RCMP) and photoinduced radical oxidation addition deactivation (PROAD) processes-is reported. First, RCMP is conducted to yield poly(methyl methacrylate) with iodide end groups (PMMA-I). In the following step, PMMA-I is used as macroinitiator for living PROAD cationic polymerization of isobutyl vinyl ether. Successful formation of the block copolymers is confirmed by 1H NMR, FT-IR, GPC, and DSC investigations.

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Synthesis of Block Copolymers by Mechanistic Transformation from Reversible Complexation Mediated Living Radical Polymerization to the Photoinduced Radical Oxidation/Addition/Deactivation Process

Abstract

Bibliographical note

ASJC Scopus Subject Areas

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