Synthesis of CuO nanostructures from Cu-based metal organic framework (MOF-199) for application as anode for Li-ion batteries

Abhik Banerjee; Upendra Singh; Vanchiappan Aravindan; Madhavi Srinivasan; Satishchandra Ogale

doi:10.1016/j.nanoen.2013.04.008

Synthesis of CuO nanostructures from Cu-based metal organic framework (MOF-199) for application as anode for Li-ion batteries

Abhik Banerjee, Upendra Singh, Vanchiappan Aravindan^*, Madhavi Srinivasan, Satishchandra Ogale

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

259 Citations (Scopus)

Abstract

We report the synthesis of CuO nanostructures by metal organic framework (MOF) based approach. Spherical shaped, phase pure CuO nanoparticles are obtained by controlled pyrolysis of Cu-based MOF. Electrochemical properties are evaluated in half-cell assembly and it is found that ~1.6mol of Li (~538mAhg^-1) is cycleable via conversion reaction. Further, MOF derived CuO retained ~90% of initial reversible capacity after 40 cycles. Rate performance studies showed the deliverable reversible capacity of ~210mAhg^-1 at high current rate of 2Ag^-1.

Original language	English
Pages (from-to)	1158-1163
Number of pages	6
Journal	Nano Energy
Volume	2
Issue number	6
DOIs	https://doi.org/10.1016/j.nanoen.2013.04.008
Publication status	Published - Nov 2013
Externally published	Yes

ASJC Scopus Subject Areas

Renewable Energy, Sustainability and the Environment
General Materials Science
Electrical and Electronic Engineering

Keywords

Anode
CuO
Li ion battery
Metal organic framework

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.nanoen.2013.04.008

Cite this

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title = "Synthesis of CuO nanostructures from Cu-based metal organic framework (MOF-199) for application as anode for Li-ion batteries",

abstract = "We report the synthesis of CuO nanostructures by metal organic framework (MOF) based approach. Spherical shaped, phase pure CuO nanoparticles are obtained by controlled pyrolysis of Cu-based MOF. Electrochemical properties are evaluated in half-cell assembly and it is found that \textasciitilde{}1.6mol of Li (\textasciitilde{}538mAhg-1) is cycleable via conversion reaction. Further, MOF derived CuO retained \textasciitilde{}90\% of initial reversible capacity after 40 cycles. Rate performance studies showed the deliverable reversible capacity of \textasciitilde{}210mAhg-1 at high current rate of 2Ag-1.",

keywords = "Anode, CuO, Li ion battery, Metal organic framework",

author = "Abhik Banerjee and Upendra Singh and Vanchiappan Aravindan and Madhavi Srinivasan and Satishchandra Ogale",

year = "2013",

month = nov,

doi = "10.1016/j.nanoen.2013.04.008",

language = "English",

volume = "2",

pages = "1158--1163",

journal = "Nano Energy",

issn = "2211-2855",

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number = "6",

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TY - JOUR

T1 - Synthesis of CuO nanostructures from Cu-based metal organic framework (MOF-199) for application as anode for Li-ion batteries

AU - Banerjee, Abhik

AU - Singh, Upendra

AU - Aravindan, Vanchiappan

AU - Srinivasan, Madhavi

AU - Ogale, Satishchandra

PY - 2013/11

Y1 - 2013/11

N2 - We report the synthesis of CuO nanostructures by metal organic framework (MOF) based approach. Spherical shaped, phase pure CuO nanoparticles are obtained by controlled pyrolysis of Cu-based MOF. Electrochemical properties are evaluated in half-cell assembly and it is found that ~1.6mol of Li (~538mAhg-1) is cycleable via conversion reaction. Further, MOF derived CuO retained ~90% of initial reversible capacity after 40 cycles. Rate performance studies showed the deliverable reversible capacity of ~210mAhg-1 at high current rate of 2Ag-1.

AB - We report the synthesis of CuO nanostructures by metal organic framework (MOF) based approach. Spherical shaped, phase pure CuO nanoparticles are obtained by controlled pyrolysis of Cu-based MOF. Electrochemical properties are evaluated in half-cell assembly and it is found that ~1.6mol of Li (~538mAhg-1) is cycleable via conversion reaction. Further, MOF derived CuO retained ~90% of initial reversible capacity after 40 cycles. Rate performance studies showed the deliverable reversible capacity of ~210mAhg-1 at high current rate of 2Ag-1.

KW - Anode

KW - CuO

KW - Li ion battery

KW - Metal organic framework

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DO - 10.1016/j.nanoen.2013.04.008

M3 - Article

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SN - 2211-2855

VL - 2

SP - 1158

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JO - Nano Energy

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IS - 6

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Synthesis of CuO nanostructures from Cu-based metal organic framework (MOF-199) for application as anode for Li-ion batteries

Abstract

ASJC Scopus Subject Areas

Keywords

UN SDGs

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