Synthesis of cyclopentadienyl ruthenium(II) complexes containing tethered functionalities

Wei Lin Janet Leong; Marc V. Garland; Lai Yoong Goh; Weng Kee Leong

doi:10.1016/j.ica.2008.09.026

Synthesis of cyclopentadienyl ruthenium(II) complexes containing tethered functionalities

Wei Lin Janet Leong, Marc V. Garland, Lai Yoong Goh, Weng Kee Leong^*

^*Corresponding author for this work

National University of Singapore

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

The reaction of [C₅H₄(CH₂)_nX]Tl (1: n = 2, X = NMe₂, OMe, CN; n = 3, X = NMe₂) with [(η⁶-C₆H₆)RuCl(μ-Cl)]₂, 2, afforded the sandwich compounds [{η⁵-C₅H₄(CH₂)_nX}Ru(η⁶-C₆H₆)]PF₆, 3, and [η⁵-C₅H₄(CH₂)_nX]₂Ru, 4. Photolytic cleavage of 3 in acetonitrile afforded the tethered products [{η⁵:κN-C₅H₄(CH₂)_nX}Ru(CH₃CN)₂]PF₆, 5.

Original language	English
Pages (from-to)	2089-2092
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	362
Issue number	6
DOIs	https://doi.org/10.1016/j.ica.2008.09.026
Publication status	Published - Apr 20 2009
Externally published	Yes

ASJC Scopus Subject Areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Keywords

Cyclopentadienyl
Ruthenium
Synthesis
Tethered functionalities

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10.1016/j.ica.2008.09.026

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title = "Synthesis of cyclopentadienyl ruthenium(II) complexes containing tethered functionalities",

abstract = "The reaction of [C5H4(CH2)nX]Tl (1: n = 2, X = NMe2, OMe, CN; n = 3, X = NMe2) with [(η6-C6H6)RuCl(μ-Cl)]2, 2, afforded the sandwich compounds [{η5-C5H4(CH2)nX}Ru(η6-C6H6)]PF6, 3, and [η5-C5H4(CH2)nX]2Ru, 4. Photolytic cleavage of 3 in acetonitrile afforded the tethered products [{η5:κN-C5H4(CH2)nX}Ru(CH3CN)2]PF6, 5.",

keywords = "Cyclopentadienyl, Ruthenium, Synthesis, Tethered functionalities",

author = "Leong, {Wei Lin Janet} and Garland, {Marc V.} and {Yoong Goh}, Lai and {Kee Leong}, Weng",

year = "2009",

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doi = "10.1016/j.ica.2008.09.026",

language = "English",

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journal = "Inorganica Chimica Acta",

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TY - JOUR

T1 - Synthesis of cyclopentadienyl ruthenium(II) complexes containing tethered functionalities

AU - Leong, Wei Lin Janet

AU - Garland, Marc V.

AU - Yoong Goh, Lai

AU - Kee Leong, Weng

PY - 2009/4/20

Y1 - 2009/4/20

N2 - The reaction of [C5H4(CH2)nX]Tl (1: n = 2, X = NMe2, OMe, CN; n = 3, X = NMe2) with [(η6-C6H6)RuCl(μ-Cl)]2, 2, afforded the sandwich compounds [{η5-C5H4(CH2)nX}Ru(η6-C6H6)]PF6, 3, and [η5-C5H4(CH2)nX]2Ru, 4. Photolytic cleavage of 3 in acetonitrile afforded the tethered products [{η5:κN-C5H4(CH2)nX}Ru(CH3CN)2]PF6, 5.

AB - The reaction of [C5H4(CH2)nX]Tl (1: n = 2, X = NMe2, OMe, CN; n = 3, X = NMe2) with [(η6-C6H6)RuCl(μ-Cl)]2, 2, afforded the sandwich compounds [{η5-C5H4(CH2)nX}Ru(η6-C6H6)]PF6, 3, and [η5-C5H4(CH2)nX]2Ru, 4. Photolytic cleavage of 3 in acetonitrile afforded the tethered products [{η5:κN-C5H4(CH2)nX}Ru(CH3CN)2]PF6, 5.

KW - Cyclopentadienyl

KW - Ruthenium

KW - Synthesis

KW - Tethered functionalities

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SP - 2089

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JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

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ER -

Synthesis of cyclopentadienyl ruthenium(II) complexes containing tethered functionalities

Abstract

ASJC Scopus Subject Areas

Keywords

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