Synthesis of Optically Active Cyclobutanones by the Photolysis of Chromium—Alkoxycarbene Complexes in the Presence of Optically Active Ene–Carbamates

Louis S. Hegedus; Roderick W. Bates; Björn C. Söderberg

doi:10.1021/ja00003a027

Synthesis of Optically Active Cyclobutanones by the Photolysis of Chromium—Alkoxycarbene Complexes in the Presence of Optically Active Ene–Carbamates

Louis S. Hegedus^*, Roderick W. Bates, Björn C. Söderberg

^*Corresponding author for this work

Colorado State University

Research output: Contribution to journal › Article › peer-review

87 Citations (Scopus)

Abstract

Optically active ene—carbamates derived from (S)-phenylglycine were allowed to photochemically react with a variety of (alkoxy)(alkyl)chromium—carbene complexes. Cyclobutanones were formed in fair to good yield with generally excellent control of stereochemistry.

Original language	English
Pages (from-to)	923-927
Number of pages	5
Journal	Journal of the American Chemical Society
Volume	113
Issue number	3
DOIs	https://doi.org/10.1021/ja00003a027
Publication status	Published - Jan 1 1991
Externally published	Yes

ASJC Scopus Subject Areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja00003a027

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title = "Synthesis of Optically Active Cyclobutanones by the Photolysis of Chromium—Alkoxycarbene Complexes in the Presence of Optically Active Ene–Carbamates",

abstract = "Optically active ene—carbamates derived from (S)-phenylglycine were allowed to photochemically react with a variety of (alkoxy)(alkyl)chromium—carbene complexes. Cyclobutanones were formed in fair to good yield with generally excellent control of stereochemistry.",

author = "Hegedus, {Louis S.} and Bates, {Roderick W.} and S{\"o}derberg, {Bj{\"o}rn C.}",

year = "1991",

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doi = "10.1021/ja00003a027",

language = "English",

volume = "113",

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journal = "Journal of the American Chemical Society",

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Synthesis of Optically Active Cyclobutanones by the Photolysis of Chromium—Alkoxycarbene Complexes in the Presence of Optically Active Ene–Carbamates. / Hegedus, Louis S.; Bates, Roderick W.; Söderberg, Björn C.
In: Journal of the American Chemical Society, Vol. 113, No. 3, 01.01.1991, p. 923-927.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis of Optically Active Cyclobutanones by the Photolysis of Chromium—Alkoxycarbene Complexes in the Presence of Optically Active Ene–Carbamates

AU - Hegedus, Louis S.

AU - Bates, Roderick W.

AU - Söderberg, Björn C.

PY - 1991/1/1

Y1 - 1991/1/1

N2 - Optically active ene—carbamates derived from (S)-phenylglycine were allowed to photochemically react with a variety of (alkoxy)(alkyl)chromium—carbene complexes. Cyclobutanones were formed in fair to good yield with generally excellent control of stereochemistry.

AB - Optically active ene—carbamates derived from (S)-phenylglycine were allowed to photochemically react with a variety of (alkoxy)(alkyl)chromium—carbene complexes. Cyclobutanones were formed in fair to good yield with generally excellent control of stereochemistry.

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JF - Journal of the American Chemical Society

IS - 3

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Synthesis of Optically Active Cyclobutanones by the Photolysis of Chromium—Alkoxycarbene Complexes in the Presence of Optically Active Ene–Carbamates

Abstract

ASJC Scopus Subject Areas

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