TY - JOUR
T1 - Synthesis of primary amines and N-methylamines by the electrophilic amination of Grignard reagents with 2-imidazolidinone O-sulfonyloxime
AU - Kitamura, Mitsuru
AU - Chiba, Shunsuke
AU - Narasaka, Koichi
PY - 2003/5
Y1 - 2003/5
N2 - 2-Imidazolidinone O-sulfonyloxime reacts with various aryl and alkyl Grignard reagents as an electrophilic amination reagent, giving N-alkylated imines. The resulting imines are transformed to primary amines and N-methyl secondary amines by hydrolysis with CsOH and LiAlH4 reduction, respectively.
AB - 2-Imidazolidinone O-sulfonyloxime reacts with various aryl and alkyl Grignard reagents as an electrophilic amination reagent, giving N-alkylated imines. The resulting imines are transformed to primary amines and N-methyl secondary amines by hydrolysis with CsOH and LiAlH4 reduction, respectively.
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U2 - 10.1246/bcsj.76.1063
DO - 10.1246/bcsj.76.1063
M3 - Article
AN - SCOPUS:0038699290
SN - 0009-2673
VL - 76
SP - 1063
EP - 1070
JO - Bulletin of the Chemical Society of Japan
JF - Bulletin of the Chemical Society of Japan
IS - 5
ER -