Synthesis of the Northern hemisphere of the briaranes

Roderick W. Bates; Attapol Pinsa; Ximin Kan

doi:10.1016/j.tet.2010.04.003

Synthesis of the Northern hemisphere of the briaranes

Roderick W. Bates, Attapol Pinsa, Ximin Kan

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

A highly functionalized fragment corresponding to the Northern hemisphere of the briaranes has been synthesized employing a sulfonyl diene Diels-Alder reaction, oxidative desulfonylation, Eschenmoser rearrangement and Keck radical allylation.

Original language	English
Pages (from-to)	6340-6348
Number of pages	9
Journal	Tetrahedron
Volume	66
Issue number	33
DOIs	https://doi.org/10.1016/j.tet.2010.04.003
Publication status	Published - Aug 14 2010
Externally published	Yes

ASJC Scopus Subject Areas

Biochemistry
Drug Discovery
Organic Chemistry

Keywords

Allylation
Cyclolactonisation
Diels-Alder
Oxidation
Sulfone

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10.1016/j.tet.2010.04.003

Cite this

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title = "Synthesis of the Northern hemisphere of the briaranes",

abstract = "A highly functionalized fragment corresponding to the Northern hemisphere of the briaranes has been synthesized employing a sulfonyl diene Diels-Alder reaction, oxidative desulfonylation, Eschenmoser rearrangement and Keck radical allylation.",

keywords = "Allylation, Cyclolactonisation, Diels-Alder, Oxidation, Sulfone",

author = "Bates, {Roderick W.} and Attapol Pinsa and Ximin Kan",

year = "2010",

month = aug,

day = "14",

doi = "10.1016/j.tet.2010.04.003",

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T1 - Synthesis of the Northern hemisphere of the briaranes

AU - Bates, Roderick W.

AU - Pinsa, Attapol

AU - Kan, Ximin

PY - 2010/8/14

Y1 - 2010/8/14

N2 - A highly functionalized fragment corresponding to the Northern hemisphere of the briaranes has been synthesized employing a sulfonyl diene Diels-Alder reaction, oxidative desulfonylation, Eschenmoser rearrangement and Keck radical allylation.

AB - A highly functionalized fragment corresponding to the Northern hemisphere of the briaranes has been synthesized employing a sulfonyl diene Diels-Alder reaction, oxidative desulfonylation, Eschenmoser rearrangement and Keck radical allylation.

KW - Allylation

KW - Cyclolactonisation

KW - Diels-Alder

KW - Oxidation

KW - Sulfone

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U2 - 10.1016/j.tet.2010.04.003

DO - 10.1016/j.tet.2010.04.003

M3 - Article

AN - SCOPUS:77955778620

SN - 0040-4020

VL - 66

SP - 6340

EP - 6348

JO - Tetrahedron

JF - Tetrahedron

IS - 33

ER -

Synthesis of the Northern hemisphere of the briaranes

Abstract

ASJC Scopus Subject Areas

Keywords

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