Synthesis of the Proposed Structure of Afzeliindanone

Rita Rita; Mohamed Husaini Bin Abdul Rahman; Sherilyn Shi Min Chong; Roderick W. Bates

doi:10.1055/s-0040-1707470

Synthesis of the Proposed Structure of Afzeliindanone

Rita Rita, Mohamed Husaini Bin Abdul Rahman, Sherilyn Shi Min Chong, Roderick W. Bates^*

^*Corresponding author for this work

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

A synthesis of the proposed structure of afzeliindanone was achieved by using an alkyne [2+2+2]-cyclotrimerization as a key step. The data for the synthetic material were found not to match those for the natural material, indicating a structural misassignment.

Original language	English
Pages (from-to)	1479-1481
Number of pages	3
Journal	Synlett
Volume	31
Issue number	15
DOIs	https://doi.org/10.1055/s-0040-1707470
Publication status	Published - Sept 16 2020
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2020 Georg Thieme Verlag. All rights reserved.

ASJC Scopus Subject Areas

Organic Chemistry

Keywords

afzeliindanone
alkynes
cyclotrimerization
indanones
rhodium catalysis

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abstract = "A synthesis of the proposed structure of afzeliindanone was achieved by using an alkyne [2+2+2]-cyclotrimerization as a key step. The data for the synthetic material were found not to match those for the natural material, indicating a structural misassignment.",

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AU - Rahman, Mohamed Husaini Bin Abdul

AU - Chong, Sherilyn Shi Min

AU - Bates, Roderick W.

PY - 2020/9/16

Y1 - 2020/9/16

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AB - A synthesis of the proposed structure of afzeliindanone was achieved by using an alkyne [2+2+2]-cyclotrimerization as a key step. The data for the synthetic material were found not to match those for the natural material, indicating a structural misassignment.

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KW - alkynes

KW - cyclotrimerization

KW - indanones

KW - rhodium catalysis

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Synthesis of the Proposed Structure of Afzeliindanone

Abstract

Bibliographical note

ASJC Scopus Subject Areas

Keywords

Access to Document

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