Synthesizing High-Volume Chemicals from CO₂ without Direct H₂ Input

Decarbonizing the chemical industry will eventually entail using CO₂ as a feedstock for chemical synthesis. However, many chemical syntheses involve CO₂ reduction using inputs such as renewable hydrogen. In this review, chemical processes are discussed that use CO₂ as an oxidant for upgrading hydrocarbon feedstocks. The captured CO₂ is inherently reduced by the hydrocarbon co-reactants without consuming molecular hydrogen or renewable electricity. This CO₂ utilization approach can be potentially applied to synthesize eight emission-intensive molecules, including olefins and epoxides. Catalytic systems and reactor concepts are discussed that can overcome practical challenges, such as thermodynamic limitations, over-oxidation, coking, and heat management. Under the best-case scenario, these hydrogen-free CO₂ reduction processes have a combined CO₂ abatement potential of approximately 1 gigatons per year and avoid the consumption of 1.24 PWh renewable electricity, based on current market demand and supply.