TY - JOUR
T1 - The chemistry of disilyne with a genuine Si-Si triple bond
T2 - Synthesis, structure, and reactivity
AU - Sekiguchi, Akira
AU - Ichinohe, Masaaki
AU - Kinjo, Rei
PY - 2006
Y1 - 2006
N2 - In this account, our recent results on the chemistry of a stable silicon-silicon triply-bonded compound, disilyne, including recent advances in the chemistry of stable alkyne analogues of heavier group 14 elements, are described. Our original extremely bulky trialkylsilyl substituent, Dis 2iPrSi [Dis = CH(SiMe3)2], has enabled the isolation of disilyne as a stable compound, which has been completely characterized by various spectroscopic techniques, as well as X-ray crystallography. Some reactivity of our isolable disilyne will be discussed.
AB - In this account, our recent results on the chemistry of a stable silicon-silicon triply-bonded compound, disilyne, including recent advances in the chemistry of stable alkyne analogues of heavier group 14 elements, are described. Our original extremely bulky trialkylsilyl substituent, Dis 2iPrSi [Dis = CH(SiMe3)2], has enabled the isolation of disilyne as a stable compound, which has been completely characterized by various spectroscopic techniques, as well as X-ray crystallography. Some reactivity of our isolable disilyne will be discussed.
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U2 - 10.1246/bcsj.79.825
DO - 10.1246/bcsj.79.825
M3 - Article
AN - SCOPUS:33750578467
SN - 0009-2673
VL - 79
SP - 825
EP - 832
JO - Bulletin of the Chemical Society of Japan
JF - Bulletin of the Chemical Society of Japan
IS - 6
ER -