The formation of aldehydes from the photochemically activated reaction of Cp*Ir(CO)(Cl)(CH2R) complexes with water

Jia Ying Lee; Wai Yip Fan; Kar Hang Garvin Mak; Weng Kee Leong

doi:10.1016/j.jorganchem.2012.11.030

The formation of aldehydes from the photochemically activated reaction of Cp*Ir(CO)(Cl)(CH₂R) complexes with water

Jia Ying Lee, Wai Yip Fan^*, Kar Hang Garvin Mak, Weng Kee Leong

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The iridium complexes Cp*Ir(CO)(Cl)(CH₂R), which do not contain any β-hydrogen atoms, react with water to form aldehydes. This reaction was found to be photochemically activated, and a possible pathway involving radical intermediates has been proposed and studied experimentally and computationally.

Original language	English
Pages (from-to)	275-280
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	724
DOIs	https://doi.org/10.1016/j.jorganchem.2012.11.030
Publication status	Published - Jan 15 2013
Externally published	Yes

ASJC Scopus Subject Areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Keywords

Aldehyde
Iridium
Photochemical activation
Transition metal radical

Access to Document

10.1016/j.jorganchem.2012.11.030

Cite this

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title = "The formation of aldehydes from the photochemically activated reaction of Cp*Ir(CO)(Cl)(CH2R) complexes with water",

abstract = "The iridium complexes Cp*Ir(CO)(Cl)(CH2R), which do not contain any β-hydrogen atoms, react with water to form aldehydes. This reaction was found to be photochemically activated, and a possible pathway involving radical intermediates has been proposed and studied experimentally and computationally.",

keywords = "Aldehyde, Iridium, Photochemical activation, Transition metal radical",

author = "Lee, {Jia Ying} and Fan, {Wai Yip} and Mak, {Kar Hang Garvin} and Leong, {Weng Kee}",

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AU - Lee, Jia Ying

AU - Fan, Wai Yip

AU - Mak, Kar Hang Garvin

AU - Leong, Weng Kee

PY - 2013/1/15

Y1 - 2013/1/15

N2 - The iridium complexes Cp*Ir(CO)(Cl)(CH2R), which do not contain any β-hydrogen atoms, react with water to form aldehydes. This reaction was found to be photochemically activated, and a possible pathway involving radical intermediates has been proposed and studied experimentally and computationally.

AB - The iridium complexes Cp*Ir(CO)(Cl)(CH2R), which do not contain any β-hydrogen atoms, react with water to form aldehydes. This reaction was found to be photochemically activated, and a possible pathway involving radical intermediates has been proposed and studied experimentally and computationally.

KW - Aldehyde

KW - Iridium

KW - Photochemical activation

KW - Transition metal radical

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