The reaction of [Cp*IrCl2]2 with 2-methyl-1-butene-3-yne: Formation of a η3-tetraenyl transition metal complex

Kar Hang Garvin Mak; Wai Yip Fan; Venugopal Shanmugham Sridevi; Weng Kee Leong

doi:10.1016/j.jorganchem.2013.04.037

The reaction of [Cp*IrCl₂]₂ with 2-methyl-1-butene-3-yne: Formation of a η³-tetraenyl transition metal complex

Kar Hang Garvin Mak, Wai Yip Fan^*, Venugopal Shanmugham Sridevi, Weng Kee Leong

^*Corresponding author for this work

Research output: Contribution to journal › Short survey › peer-review

3 Citations (Scopus)

Abstract

Reaction of the dimeric species [Cp*IrCl₂]₂ with 2-methyl-1-butene-3-yne results in C-C bond formation between two alkyne molecules and their coordination to an iridium center to form a complex containing a η³-tetraenyl ligand. The reaction pathway has been studied experimentally and computationally.

Original language	English
Pages (from-to)	52-56
Number of pages	5
Journal	Journal of Organometallic Chemistry
Volume	739
DOIs	https://doi.org/10.1016/j.jorganchem.2013.04.037
Publication status	Published - Sept 1 2013
Externally published	Yes

ASJC Scopus Subject Areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Keywords

C-C coupling
Conjugated enyne
Iridium h3-tetraenyl

Access to Document

10.1016/j.jorganchem.2013.04.037

Cite this

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title = "The reaction of [Cp*IrCl2]2 with 2-methyl-1-butene-3-yne: Formation of a η3-tetraenyl transition metal complex",

abstract = "Reaction of the dimeric species [Cp*IrCl2]2 with 2-methyl-1-butene-3-yne results in C-C bond formation between two alkyne molecules and their coordination to an iridium center to form a complex containing a η3-tetraenyl ligand. The reaction pathway has been studied experimentally and computationally.",

keywords = "C-C coupling, Conjugated enyne, Iridium h3-tetraenyl",

author = "Mak, {Kar Hang Garvin} and Fan, {Wai Yip} and Sridevi, {Venugopal Shanmugham} and Leong, {Weng Kee}",

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doi = "10.1016/j.jorganchem.2013.04.037",

language = "English",

volume = "739",

pages = "52--56",

journal = "Journal of Organometallic Chemistry",

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T1 - The reaction of [Cp*IrCl2]2 with 2-methyl-1-butene-3-yne

T2 - Formation of a η3-tetraenyl transition metal complex

AU - Mak, Kar Hang Garvin

AU - Fan, Wai Yip

AU - Sridevi, Venugopal Shanmugham

AU - Leong, Weng Kee

PY - 2013/9/1

Y1 - 2013/9/1

N2 - Reaction of the dimeric species [Cp*IrCl2]2 with 2-methyl-1-butene-3-yne results in C-C bond formation between two alkyne molecules and their coordination to an iridium center to form a complex containing a η3-tetraenyl ligand. The reaction pathway has been studied experimentally and computationally.

AB - Reaction of the dimeric species [Cp*IrCl2]2 with 2-methyl-1-butene-3-yne results in C-C bond formation between two alkyne molecules and their coordination to an iridium center to form a complex containing a η3-tetraenyl ligand. The reaction pathway has been studied experimentally and computationally.

KW - C-C coupling

KW - Conjugated enyne

KW - Iridium h3-tetraenyl

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U2 - 10.1016/j.jorganchem.2013.04.037

DO - 10.1016/j.jorganchem.2013.04.037

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EP - 56

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

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