The thermolysis products of Os3(CO)11(AsPh3)

Chuen Tse Tay; Weng Kee Leong

doi:10.1016/S0022-328X(01)00673-8

The thermolysis products of Os₃(CO)₁₁(AsPh₃)

Chuen Tse Tay, Weng Kee Leong^*

^*Corresponding author for this work

National University of Singapore

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

Thermolysis of the substituted triosmium cluster Os₃(CO)₁₁(AsPh₃) in refluxing nonane gave four major products: Os₃(μ₃-AsPh)(μ₃,η²-C₆H₄)(CO)₉, Os₃(μ-H)(μ-AsPh₂)(μ₃,η² -C₆H₄)(CO)₉, Os₃(μ-AsPh₂)₂(μ₃,η²-C₆H₄)(CO)₇ and Os₃(μ₃-AsPh)(μ₃,η²-C₆H₄)(CO)₈(AsPh₃). All the new clusters have been characterised by spectroscopy and single-crystal X-ray crystallographic studies.

Original language	English
Pages (from-to)	231-235
Number of pages	5
Journal	Journal of Organometallic Chemistry
Volume	625
Issue number	2
DOIs	https://doi.org/10.1016/S0022-328X(01)00673-8
Publication status	Published - Apr 22 2001
Externally published	Yes

ASJC Scopus Subject Areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Keywords

Arsenic
Clusters
Osmium

Access to Document

10.1016/S0022-328X(01)00673-8

Cite this

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title = "The thermolysis products of Os3(CO)11(AsPh3)",

abstract = "Thermolysis of the substituted triosmium cluster Os3(CO)11(AsPh3) in refluxing nonane gave four major products: Os3(μ3-AsPh)(μ3,η2-C6 H4)(CO)9, Os3(μ-H)(μ-AsPh2)(μ3,η2 -C6H4)(CO)9, Os3(μ-AsPh2)2(μ3,η2-C6H4)(CO)7 and Os3(μ3-AsPh)(μ3,η2-C6 H4)(CO)8(AsPh3). All the new clusters have been characterised by spectroscopy and single-crystal X-ray crystallographic studies.",

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T1 - The thermolysis products of Os3(CO)11(AsPh3)

AU - Tay, Chuen Tse

AU - Leong, Weng Kee

PY - 2001/4/22

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N2 - Thermolysis of the substituted triosmium cluster Os3(CO)11(AsPh3) in refluxing nonane gave four major products: Os3(μ3-AsPh)(μ3,η2-C6 H4)(CO)9, Os3(μ-H)(μ-AsPh2)(μ3,η2 -C6H4)(CO)9, Os3(μ-AsPh2)2(μ3,η2-C6H4)(CO)7 and Os3(μ3-AsPh)(μ3,η2-C6 H4)(CO)8(AsPh3). All the new clusters have been characterised by spectroscopy and single-crystal X-ray crystallographic studies.

AB - Thermolysis of the substituted triosmium cluster Os3(CO)11(AsPh3) in refluxing nonane gave four major products: Os3(μ3-AsPh)(μ3,η2-C6 H4)(CO)9, Os3(μ-H)(μ-AsPh2)(μ3,η2 -C6H4)(CO)9, Os3(μ-AsPh2)2(μ3,η2-C6H4)(CO)7 and Os3(μ3-AsPh)(μ3,η2-C6 H4)(CO)8(AsPh3). All the new clusters have been characterised by spectroscopy and single-crystal X-ray crystallographic studies.

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KW - Osmium

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