Thermolysis of polymeric [Ru(CO)4]∞ to metallic ruthenium: Molecular shape of the precursor affects the nanoparticle shape

Chunxiang Li; Weng Kee Leong

doi:10.1021/la8019233

Thermolysis of polymeric [Ru(CO)₄]_∞ to metallic ruthenium: Molecular shape of the precursor affects the nanoparticle shape

Chunxiang Li, Weng Kee Leong

National University of Singapore

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Pyrolysis of the organometallic polymer [Ru(CO)₄] _∞ affords metallic ruthenium nanofibers. The molecular structure, especially the presence of metal-metal bonds, appears to direct the aggregation of the metal atom chains upon loss of the carbonyl ligands.

Original language	English
Pages (from-to)	12040-12041
Number of pages	2
Journal	Langmuir
Volume	24
Issue number	20
DOIs	https://doi.org/10.1021/la8019233
Publication status	Published - Oct 21 2008
Externally published	Yes

ASJC Scopus Subject Areas

General Materials Science
Condensed Matter Physics
Surfaces and Interfaces
Spectroscopy
Electrochemistry

Access to Document

10.1021/la8019233

Cite this

@article{c5c35f5c9a2a45088fe3deeb762d3f6f,

title = "Thermolysis of polymeric [Ru(CO)4]∞ to metallic ruthenium: Molecular shape of the precursor affects the nanoparticle shape",

abstract = "Pyrolysis of the organometallic polymer [Ru(CO)4] ∞ affords metallic ruthenium nanofibers. The molecular structure, especially the presence of metal-metal bonds, appears to direct the aggregation of the metal atom chains upon loss of the carbonyl ligands.",

author = "Chunxiang Li and Leong, {Weng Kee}",

year = "2008",

month = oct,

day = "21",

doi = "10.1021/la8019233",

language = "English",

volume = "24",

pages = "12040--12041",

journal = "Langmuir",

issn = "0743-7463",

publisher = "American Chemical Society",

number = "20",

}

TY - JOUR

T1 - Thermolysis of polymeric [Ru(CO)4]∞ to metallic ruthenium

T2 - Molecular shape of the precursor affects the nanoparticle shape

AU - Li, Chunxiang

AU - Leong, Weng Kee

PY - 2008/10/21

Y1 - 2008/10/21

N2 - Pyrolysis of the organometallic polymer [Ru(CO)4] ∞ affords metallic ruthenium nanofibers. The molecular structure, especially the presence of metal-metal bonds, appears to direct the aggregation of the metal atom chains upon loss of the carbonyl ligands.

AB - Pyrolysis of the organometallic polymer [Ru(CO)4] ∞ affords metallic ruthenium nanofibers. The molecular structure, especially the presence of metal-metal bonds, appears to direct the aggregation of the metal atom chains upon loss of the carbonyl ligands.

UR - http://www.scopus.com/inward/record.url?scp=55549131907&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=55549131907&partnerID=8YFLogxK

U2 - 10.1021/la8019233

DO - 10.1021/la8019233

M3 - Article

AN - SCOPUS:55549131907

SN - 0743-7463

VL - 24

SP - 12040

EP - 12041

JO - Langmuir

JF - Langmuir

IS - 20

ER -

Thermolysis of polymeric [Ru(CO)₄]_∞ to metallic ruthenium: Molecular shape of the precursor affects the nanoparticle shape

Abstract

ASJC Scopus Subject Areas

Access to Document

Other files and links

Fingerprint

Cite this