Time-resolved terahertz spectroscopy of conjugated polymer/CdSe nanorod composites

David G. Cooke, Jun Y. Lek, Frederik C. Krebs, Yeng Ming Lam, Peter Uhd Jepsen

Research output: Chapter in Book/Report/Conference proceedingConference contribution

3 Citations (Scopus)

Abstract

We report ultrafast carrier dynamics in hybrid CdSe nanorod/poly(3- hexythiophene) (P3HT) bulk heterojunction films measured by time-resolved terahertz spectroscopy, and compare to the well studied P3HT/phenyl-C61-butyric acid methyl ester (PCBM) blend. Both films show an improved peak photoconductivity compared to P3HT alone, consistent with efficient charge transfer. The photoconductivity dynamics show fast, picosecond trapping or recombination in the hybrid blend while the all-organic film shows no such loss of mobile charge over ns time scales. The ac conductivity for all samples is well described by a Kramers-Kronig compatible Jonscher-type power law with exponent between 0.5 and 1 suggesting that interchain hopping in the polymer or between nanorods occurs at frequencies higher than 3 THz immediately after photoexcitation.

Original languageEnglish
Title of host publicationUltrafast Phenomena in Semiconductors and Nanostructure Materials XIV
PublisherSPIE
ISBN (Print)9780819479969
DOIs
Publication statusPublished - 2010
Externally publishedYes
EventUltrafast Phenomena in Semiconductors and Nanostructure Materials XIV - San Francisco, CA, United States
Duration: Jan 24 2010Jan 27 2010

Publication series

NameProceedings of SPIE - The International Society for Optical Engineering
Volume7600
ISSN (Print)0277-786X

Conference

ConferenceUltrafast Phenomena in Semiconductors and Nanostructure Materials XIV
Country/TerritoryUnited States
CitySan Francisco, CA
Period1/24/101/27/10

ASJC Scopus Subject Areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Computer Science Applications
  • Applied Mathematics
  • Electrical and Electronic Engineering

Keywords

  • Bulk heterojunctions
  • Carrier dynamics
  • Conductivity
  • Conjugated polymers
  • Nanorods
  • Terahertz
  • Ultrafast

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