Translational and rotational critical-like behaviors in the glass transition of colloidal ellipsoid monolayers

Zhongyu Zheng, Ran Ni, Yuren Wang*, Yilong Han*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

17 Citations (Scopus)

Abstract

Critical-like behaviors have been found in translational degrees of freedom near the glass transition of spherical particle systems mainly with local polycrystalline structures, but it is not clear if criticality exists in more general glassy systems composed of nonspherical particles without crystalline structures. Here, through experiments and simulations, we show critical-like behaviors in both translational and rotational degrees of freedom in monolayers of monodisperse colloidal ellipsoids in the absence of crystalline orders. We find rich features of the Ising-like criticality in structure and slow dynamics at the ideal glass transition point φ0, showing the thermodynamic nature of glass transition at φ0. A dynamic criticality is found at the mode-coupling critical point φcfor the fast-moving clusters whose critical exponents increase linearly with fragility, reflecting a dynamic glass transition. These results cast light on the glass transition and explain the mystery that the dynamic correlation lengths diverge at two different temperatures.

Original languageEnglish
Article numbereabd1958
JournalScience advances
Volume7
Issue number3
DOIs
Publication statusPublished - Jan 15 2021
Externally publishedYes

Bibliographical note

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© 2021 American Association for the Advancement of Science. All rights reserved.

ASJC Scopus Subject Areas

  • General

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