Use of alcohol as initiator for reversible chain transfer catalyzed polymerization

Jeongsik Kim; Akihiro Nomura; Takeshi Fukuda; Atsushi Goto; Yoshinobu Tsujii

doi:10.1002/mren.200900051

Use of alcohol as initiator for reversible chain transfer catalyzed polymerization

Jeongsik Kim, Akihiro Nomura, Takeshi Fukuda, Atsushi Goto^*, Yoshinobu Tsujii

^*Corresponding author for this work

Kyoto University

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

A novel initiation system, using a hydroxyl group as an initiating moiety, was developed for reversible chain transfer catalyzed polymerization (RTCP), a living radical polymerization. The hydroxyl (alcohol) group was reacted with an iodinating agent and a monomer (M), giving a dormant species RO-M-I (I = iodine). It was prepared in the polymerization medium (monomer) and used in the polymerization without the purification, leading to a one-pot RTCP from a hydroxyl group (an alcohol).

Original language	English
Pages (from-to)	272-277
Number of pages	6
Journal	Macromolecular Reaction Engineering
Volume	4
Issue number	3-4
DOIs	https://doi.org/10.1002/mren.200900051
Publication status	Published - Mar 2010
Externally published	Yes

ASJC Scopus Subject Areas

General Chemistry
General Chemical Engineering
Polymers and Plastics

Keywords

Catalysts
Initiators
Living polymerization
Radical polymerization
Reversible chain transfer catalyzed polymerization

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10.1002/mren.200900051

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title = "Use of alcohol as initiator for reversible chain transfer catalyzed polymerization",

abstract = "A novel initiation system, using a hydroxyl group as an initiating moiety, was developed for reversible chain transfer catalyzed polymerization (RTCP), a living radical polymerization. The hydroxyl (alcohol) group was reacted with an iodinating agent and a monomer (M), giving a dormant species RO-M-I (I = iodine). It was prepared in the polymerization medium (monomer) and used in the polymerization without the purification, leading to a one-pot RTCP from a hydroxyl group (an alcohol).",

keywords = "Catalysts, Initiators, Living polymerization, Radical polymerization, Reversible chain transfer catalyzed polymerization",

author = "Jeongsik Kim and Akihiro Nomura and Takeshi Fukuda and Atsushi Goto and Yoshinobu Tsujii",

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journal = "Macromolecular Reaction Engineering",

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T1 - Use of alcohol as initiator for reversible chain transfer catalyzed polymerization

AU - Kim, Jeongsik

AU - Nomura, Akihiro

AU - Fukuda, Takeshi

AU - Goto, Atsushi

AU - Tsujii, Yoshinobu

PY - 2010/3

Y1 - 2010/3

N2 - A novel initiation system, using a hydroxyl group as an initiating moiety, was developed for reversible chain transfer catalyzed polymerization (RTCP), a living radical polymerization. The hydroxyl (alcohol) group was reacted with an iodinating agent and a monomer (M), giving a dormant species RO-M-I (I = iodine). It was prepared in the polymerization medium (monomer) and used in the polymerization without the purification, leading to a one-pot RTCP from a hydroxyl group (an alcohol).

AB - A novel initiation system, using a hydroxyl group as an initiating moiety, was developed for reversible chain transfer catalyzed polymerization (RTCP), a living radical polymerization. The hydroxyl (alcohol) group was reacted with an iodinating agent and a monomer (M), giving a dormant species RO-M-I (I = iodine). It was prepared in the polymerization medium (monomer) and used in the polymerization without the purification, leading to a one-pot RTCP from a hydroxyl group (an alcohol).

KW - Catalysts

KW - Initiators

KW - Living polymerization

KW - Radical polymerization

KW - Reversible chain transfer catalyzed polymerization

UR - http://www.scopus.com/inward/record.url?scp=77954594506&partnerID=8YFLogxK

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DO - 10.1002/mren.200900051

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JO - Macromolecular Reaction Engineering

JF - Macromolecular Reaction Engineering

IS - 3-4

ER -

Use of alcohol as initiator for reversible chain transfer catalyzed polymerization

Abstract

ASJC Scopus Subject Areas

Keywords

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