Abstract
Aluminum (Al)-ion batteries can be an attractive alternative to lithium-ion batteries because of low costs, high volumetric capacities and dendrite-free formation when Al is used as anode. However, there are limited cathode materials for Al-ion batteries that can deliver satisfactory electrochemical performance, especially cycling stability. The major reason for that is the sluggish kinetics of ion intercalation/deintercalation, resulting from large coulombic attraction between Al3+ and cathodes. Herein, a concept of hybrid Al−Li-ion batteries is proposed to circumvent the poor Al3+ ions insertion/extraction kinetics in Al-ion batteries, and maintain the dendrite-free characteristics of Al-ion batteries. The high volumetric capacity (32.5 mAh/cm3 at 100 mA/cm3, based on the total volume of cathode), enhanced rate capability (21.5 mAh/cm3 at 1000 mA/cm3) and excellent cycling performance (70.1 % retention after 3000 cycles) have been achieved in the hybrid Al−Li-ion battery composed of vanadium oxide nanosheets on carbon fibers as cathode and Al as anode in a mixed [EMIM][Cl]/AlCl3/LiCl electrolyte. Combining with the good flexibility of cathode and anode, the hybrid Al−Li-ion battery maintains structural and capacity stability under different bending angles. This study unveils a safe, cost-effective and flexible hybrid Al−Li-ion battery that presents highly competitive advantages among various energy storage devices.
Original language | English |
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Pages (from-to) | 205-212 |
Number of pages | 8 |
Journal | Batteries and Supercaps |
Volume | 2 |
Issue number | 3 |
DOIs | |
Publication status | Published - Mar 1 2019 |
Externally published | Yes |
Bibliographical note
Publisher Copyright:© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
ASJC Scopus Subject Areas
- Energy Engineering and Power Technology
- Electrical and Electronic Engineering
- Electrochemistry
Keywords
- dendrite-free
- flexible batteries
- hybrid aluminium-lithium-ion batteries
- kinetics
- nanostructures