Vanadium Oxide Nanosheets for Flexible Dendrite-Free Hybrid Aluminium-Lithium-Ion Batteries with Excellent Cycling Performance

Xuefei Gong, Jingwei Chen, Shaohui Li, Lars Mohrhusen, Katharina Al-Shamery, Pooi See Lee*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

7 Citations (Scopus)

Abstract

Aluminum (Al)-ion batteries can be an attractive alternative to lithium-ion batteries because of low costs, high volumetric capacities and dendrite-free formation when Al is used as anode. However, there are limited cathode materials for Al-ion batteries that can deliver satisfactory electrochemical performance, especially cycling stability. The major reason for that is the sluggish kinetics of ion intercalation/deintercalation, resulting from large coulombic attraction between Al3+ and cathodes. Herein, a concept of hybrid Al−Li-ion batteries is proposed to circumvent the poor Al3+ ions insertion/extraction kinetics in Al-ion batteries, and maintain the dendrite-free characteristics of Al-ion batteries. The high volumetric capacity (32.5 mAh/cm3 at 100 mA/cm3, based on the total volume of cathode), enhanced rate capability (21.5 mAh/cm3 at 1000 mA/cm3) and excellent cycling performance (70.1 % retention after 3000 cycles) have been achieved in the hybrid Al−Li-ion battery composed of vanadium oxide nanosheets on carbon fibers as cathode and Al as anode in a mixed [EMIM][Cl]/AlCl3/LiCl electrolyte. Combining with the good flexibility of cathode and anode, the hybrid Al−Li-ion battery maintains structural and capacity stability under different bending angles. This study unveils a safe, cost-effective and flexible hybrid Al−Li-ion battery that presents highly competitive advantages among various energy storage devices.

Original languageEnglish
Pages (from-to)205-212
Number of pages8
JournalBatteries and Supercaps
Volume2
Issue number3
DOIs
Publication statusPublished - Mar 1 2019
Externally publishedYes

Bibliographical note

Publisher Copyright:
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

ASJC Scopus Subject Areas

  • Energy Engineering and Power Technology
  • Electrical and Electronic Engineering
  • Electrochemistry

Keywords

  • dendrite-free
  • flexible batteries
  • hybrid aluminium-lithium-ion batteries
  • kinetics
  • nanostructures

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