A general approach to non-fullerene electron acceptors based on the corannulene motif

Viktor Barát; Maja Budanović; Dzeneta Halilovic; June Huh; Richard D. Webster; Surendra H. Mahadevegowda; Mihaiela C. Stuparu

doi:10.1039/c9cc00327d

A general approach to non-fullerene electron acceptors based on the corannulene motif

Viktor Barát, Maja Budanović, Dzeneta Halilovic, June Huh, Richard D. Webster, Surendra H. Mahadevegowda, Mihaiela C. Stuparu^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

Here, we show that oxidation of exo-cyclic sulfur atoms enhances the molecular reduction potential of non-planar polycyclic aromatic hydrocarbons and allows for a systematic bridging of the electron affinity gap between corannulene, a fragment of fullerene C₆₀, and the prevalent fullerene-based electron acceptor phenyl-C₆₁-butyric acid methyl ester (PCBM).

Original language	English
Pages (from-to)	3113-3116
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	21
DOIs	https://doi.org/10.1039/c9cc00327d
Publication status	Published - 2019
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2019 The Royal Society of Chemistry.

ASJC Scopus Subject Areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c9cc00327d

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abstract = "Here, we show that oxidation of exo-cyclic sulfur atoms enhances the molecular reduction potential of non-planar polycyclic aromatic hydrocarbons and allows for a systematic bridging of the electron affinity gap between corannulene, a fragment of fullerene C60, and the prevalent fullerene-based electron acceptor phenyl-C61-butyric acid methyl ester (PCBM).",

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AU - Barát, Viktor

AU - Budanović, Maja

AU - Halilovic, Dzeneta

AU - Huh, June

AU - Webster, Richard D.

AU - Mahadevegowda, Surendra H.

AU - Stuparu, Mihaiela C.

PY - 2019

Y1 - 2019

N2 - Here, we show that oxidation of exo-cyclic sulfur atoms enhances the molecular reduction potential of non-planar polycyclic aromatic hydrocarbons and allows for a systematic bridging of the electron affinity gap between corannulene, a fragment of fullerene C60, and the prevalent fullerene-based electron acceptor phenyl-C61-butyric acid methyl ester (PCBM).

AB - Here, we show that oxidation of exo-cyclic sulfur atoms enhances the molecular reduction potential of non-planar polycyclic aromatic hydrocarbons and allows for a systematic bridging of the electron affinity gap between corannulene, a fragment of fullerene C60, and the prevalent fullerene-based electron acceptor phenyl-C61-butyric acid methyl ester (PCBM).

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JO - Chemical Communications

JF - Chemical Communications

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ER -

A general approach to non-fullerene electron acceptors based on the corannulene motif

Abstract

Bibliographical note

ASJC Scopus Subject Areas

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