Aerobic Copper Catalysis for Tandem Oxy-N-alkenylation of [1,2,3]Triazolo[1,5-a]pyridines

Sreekumar Pankajakshan; Wei Li Ang; Sivarampanicker Sreejith; Mihaiela Corina Stuparu; Teck Peng Loh

doi:10.1002/adsc.201600580

Aerobic Copper Catalysis for Tandem Oxy-N-alkenylation of [1,2,3]Triazolo[1,5-a]pyridines

Sreekumar Pankajakshan^*, Wei Li Ang, Sivarampanicker Sreejith, Mihaiela Corina Stuparu, Teck Peng Loh

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

N-Alkenylated triazolinone ylides were generated through copper-catalyzed oxy-N-alkenylation of triazolopyridines. The mechanistic course of this aerobic tandem reaction has been experimentally elucidated and primary photophysical data of the ylide products are also given. (Figure presented.).

Original language	English
Pages (from-to)	3034-3038
Number of pages	5
Journal	Advanced Synthesis and Catalysis
Volume	358
Issue number	19
DOIs	https://doi.org/10.1002/adsc.201600580
Publication status	Published - Oct 6 2016
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

ASJC Scopus Subject Areas

Catalysis
Organic Chemistry

Keywords

aerobic oxidation
copper catalysis
fluorescence
nitrogen ylides
triazolopyridines

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10.1002/adsc.201600580

Cite this

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title = "Aerobic Copper Catalysis for Tandem Oxy-N-alkenylation of [1,2,3]Triazolo[1,5-a]pyridines",

abstract = "N-Alkenylated triazolinone ylides were generated through copper-catalyzed oxy-N-alkenylation of triazolopyridines. The mechanistic course of this aerobic tandem reaction has been experimentally elucidated and primary photophysical data of the ylide products are also given. (Figure presented.).",

keywords = "aerobic oxidation, copper catalysis, fluorescence, nitrogen ylides, triazolopyridines",

author = "Sreekumar Pankajakshan and Ang, {Wei Li} and Sivarampanicker Sreejith and Stuparu, {Mihaiela Corina} and Loh, {Teck Peng}",

note = "Publisher Copyright: {\textcopyright} 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",

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doi = "10.1002/adsc.201600580",

language = "English",

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T1 - Aerobic Copper Catalysis for Tandem Oxy-N-alkenylation of [1,2,3]Triazolo[1,5-a]pyridines

AU - Pankajakshan, Sreekumar

AU - Ang, Wei Li

AU - Sreejith, Sivarampanicker

AU - Stuparu, Mihaiela Corina

AU - Loh, Teck Peng

PY - 2016/10/6

Y1 - 2016/10/6

N2 - N-Alkenylated triazolinone ylides were generated through copper-catalyzed oxy-N-alkenylation of triazolopyridines. The mechanistic course of this aerobic tandem reaction has been experimentally elucidated and primary photophysical data of the ylide products are also given. (Figure presented.).

AB - N-Alkenylated triazolinone ylides were generated through copper-catalyzed oxy-N-alkenylation of triazolopyridines. The mechanistic course of this aerobic tandem reaction has been experimentally elucidated and primary photophysical data of the ylide products are also given. (Figure presented.).

KW - aerobic oxidation

KW - copper catalysis

KW - fluorescence

KW - nitrogen ylides

KW - triazolopyridines

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U2 - 10.1002/adsc.201600580

DO - 10.1002/adsc.201600580

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JO - Advanced Synthesis and Catalysis

JF - Advanced Synthesis and Catalysis

IS - 19

ER -

Aerobic Copper Catalysis for Tandem Oxy-N-alkenylation of [1,2,3]Triazolo[1,5-a]pyridines

Abstract

Bibliographical note

ASJC Scopus Subject Areas

Keywords

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