Amidinatoamidosilylene-Dibromodiborene

Jun Fan; Ming Chung Yang; Ming Der Su; Cheuk Wai So

doi:10.1021/acs.inorgchem.1c02541

Amidinatoamidosilylene-Dibromodiborene

Jun Fan, Ming Chung Yang, Ming Der Su^*, Cheuk Wai So^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

The amidinatoamidosilylene [LSiNMe2] [1; L = PhC(NtBu)2] was reacted with B2Br4(SMe2)2 in toluene at room temperature to form the bis(silylene)tetrabromodiborane [L{Me2N}Si]2B2Br4 (2). It was then reacted with excess KC8 in tetrahydrofuran at room temperature to afford the bis(silylene)dibromodiborene [L{Me2N}Si]2B2Br2 (3).

Original language	English
Pages (from-to)	16065-16069
Number of pages	5
Journal	Inorganic Chemistry
Volume	60
Issue number	21
DOIs	https://doi.org/10.1021/acs.inorgchem.1c02541
Publication status	Published - Nov 1 2021
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2021 American Chemical Society.

ASJC Scopus Subject Areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/acs.inorgchem.1c02541

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title = "Amidinatoamidosilylene-Dibromodiborene",

abstract = "The amidinatoamidosilylene [LSiNMe2] [1; L = PhC(NtBu)2] was reacted with B2Br4(SMe2)2 in toluene at room temperature to form the bis(silylene)tetrabromodiborane [L{Me2N}Si]2B2Br4 (2). It was then reacted with excess KC8 in tetrahydrofuran at room temperature to afford the bis(silylene)dibromodiborene [L{Me2N}Si]2B2Br2 (3).",

author = "Jun Fan and Yang, {Ming Chung} and Su, {Ming Der} and So, {Cheuk Wai}",

note = "Publisher Copyright: {\textcopyright} 2021 American Chemical Society.",

year = "2021",

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doi = "10.1021/acs.inorgchem.1c02541",

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T1 - Amidinatoamidosilylene-Dibromodiborene

AU - Fan, Jun

AU - Yang, Ming Chung

AU - Su, Ming Der

AU - So, Cheuk Wai

PY - 2021/11/1

Y1 - 2021/11/1

N2 - The amidinatoamidosilylene [LSiNMe2] [1; L = PhC(NtBu)2] was reacted with B2Br4(SMe2)2 in toluene at room temperature to form the bis(silylene)tetrabromodiborane [L{Me2N}Si]2B2Br4 (2). It was then reacted with excess KC8 in tetrahydrofuran at room temperature to afford the bis(silylene)dibromodiborene [L{Me2N}Si]2B2Br2 (3).

AB - The amidinatoamidosilylene [LSiNMe2] [1; L = PhC(NtBu)2] was reacted with B2Br4(SMe2)2 in toluene at room temperature to form the bis(silylene)tetrabromodiborane [L{Me2N}Si]2B2Br4 (2). It was then reacted with excess KC8 in tetrahydrofuran at room temperature to afford the bis(silylene)dibromodiborene [L{Me2N}Si]2B2Br2 (3).

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 21

ER -

Amidinatoamidosilylene-Dibromodiborene

Abstract

Bibliographical note

ASJC Scopus Subject Areas

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