Reactivity of a disilylene [{PhC(NBut)2}Si] 2 toward bromine: Synthesis and characterization of a stable monomeric bromosilylene

Hui Xian Yeong; Kai Chung Lau; Hong Wei Xi; Kok Hwa Lim; Cheuk Wai So

doi:10.1021/ic9021382

Reactivity of a disilylene [{PhC(NBu^t)₂}Si] ₂ toward bromine: Synthesis and characterization of a stable monomeric bromosilylene

Hui Xian Yeong, Kai Chung Lau, Hong Wei Xi, Kok Hwa Lim, Cheuk Wai So^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

The reaction of the disilylene [{PhC(NBu^t)₂}Si] ₂ (1) with 1 equiv of bromine in toluene afforded novel monomeric bromosilylene [{PhC(NBu^t)₂}SiBr] (2). The result shows that the Si^I-Si^I bond in 1 was cleaved by bromine. An X-ray structure of compound 2 has been determined.

Original language	English
Pages (from-to)	371-373
Number of pages	3
Journal	Inorganic Chemistry
Volume	49
Issue number	2
DOIs	https://doi.org/10.1021/ic9021382
Publication status	Published - Jan 18 2010
Externally published	Yes

ASJC Scopus Subject Areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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abstract = "The reaction of the disilylene [{PhC(NBut)2}Si] 2 (1) with 1 equiv of bromine in toluene afforded novel monomeric bromosilylene [{PhC(NBut)2}SiBr] (2). The result shows that the SiI-SiI bond in 1 was cleaved by bromine. An X-ray structure of compound 2 has been determined.",

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T1 - Reactivity of a disilylene [{PhC(NBut)2}Si] 2 toward bromine

T2 - Synthesis and characterization of a stable monomeric bromosilylene

AU - Yeong, Hui Xian

AU - Lau, Kai Chung

AU - Xi, Hong Wei

AU - Lim, Kok Hwa

AU - So, Cheuk Wai

PY - 2010/1/18

Y1 - 2010/1/18

N2 - The reaction of the disilylene [{PhC(NBut)2}Si] 2 (1) with 1 equiv of bromine in toluene afforded novel monomeric bromosilylene [{PhC(NBut)2}SiBr] (2). The result shows that the SiI-SiI bond in 1 was cleaved by bromine. An X-ray structure of compound 2 has been determined.

AB - The reaction of the disilylene [{PhC(NBut)2}Si] 2 (1) with 1 equiv of bromine in toluene afforded novel monomeric bromosilylene [{PhC(NBut)2}SiBr] (2). The result shows that the SiI-SiI bond in 1 was cleaved by bromine. An X-ray structure of compound 2 has been determined.

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Reactivity of a disilylene [{PhC(NBu^t)₂}Si] ₂ toward bromine: Synthesis and characterization of a stable monomeric bromosilylene

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