Reactivity of a tin(II) 1,3-benzodi(thiophosphinoyl)methanediide complex toward gallium, germanium, and zinc compounds

Yi Fan Yang; Rakesh Ganguly; Yongxin Li; Cheuk Wai So

doi:10.1021/om400141j

Reactivity of a tin(II) 1,3-benzodi(thiophosphinoyl)methanediide complex toward gallium, germanium, and zinc compounds

Yi Fan Yang, Rakesh Ganguly, Yongxin Li, Cheuk Wai So^*

^*Corresponding author for this work

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

The reactivity of the tin(II) 1,3-benzodi(thiophosphinoyl)methanediide complex [{μ-1,3-C₆H₄(PhPS)₂C}Sn]₂ (1) toward GaCl₃, GeCl₄, and ZnEt₂ is described. The reaction of 1 with 1.7 equiv of GeCl₄ in CH ₂Cl₂ at room temperature afforded [1,3-C₆H ₄(PhPS)₂C(GeCl₃)SnCl]₂ (2). Treatment of 1 with 1.7 equiv of ZnEt₂ in refluxing toluene afforded [{1,3-C₆H₄(PhPS)₂CSnEt₂}(μ-ZnS)] ₂ (3). Compound 1 also reacted with 1.7 equiv of GaCl₃ in CH₂Cl₂ to afford [1,3-C₆H₄(PhPS) ₂C(Sn)(GaCl₃)] (4). Compounds 2-4 have been characterized by NMR spectroscopy and X-ray crystallography.

Original language	English
Pages (from-to)	2643-2648
Number of pages	6
Journal	Organometallics
Volume	32
Issue number	9
DOIs	https://doi.org/10.1021/om400141j
Publication status	Published - May 13 2013
Externally published	Yes

ASJC Scopus Subject Areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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@article{63436dd9059e448cb09c9cc6f54f8afd,

title = "Reactivity of a tin(II) 1,3-benzodi(thiophosphinoyl)methanediide complex toward gallium, germanium, and zinc compounds",

abstract = "The reactivity of the tin(II) 1,3-benzodi(thiophosphinoyl)methanediide complex [{μ-1,3-C6H4(PhPS)2C}Sn]2 (1) toward GaCl3, GeCl4, and ZnEt2 is described. The reaction of 1 with 1.7 equiv of GeCl4 in CH 2Cl2 at room temperature afforded [1,3-C6H 4(PhPS)2C(GeCl3)SnCl]2 (2). Treatment of 1 with 1.7 equiv of ZnEt2 in refluxing toluene afforded [{1,3-C6H4(PhPS)2CSnEt2}(μ-ZnS)] 2 (3). Compound 1 also reacted with 1.7 equiv of GaCl3 in CH2Cl2 to afford [1,3-C6H4(PhPS) 2C(Sn)(GaCl3)] (4). Compounds 2-4 have been characterized by NMR spectroscopy and X-ray crystallography.",

author = "Yang, {Yi Fan} and Rakesh Ganguly and Yongxin Li and So, {Cheuk Wai}",

year = "2013",

month = may,

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doi = "10.1021/om400141j",

language = "English",

volume = "32",

pages = "2643--2648",

journal = "Organometallics",

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publisher = "American Chemical Society",

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TY - JOUR

T1 - Reactivity of a tin(II) 1,3-benzodi(thiophosphinoyl)methanediide complex toward gallium, germanium, and zinc compounds

AU - Yang, Yi Fan

AU - Ganguly, Rakesh

AU - Li, Yongxin

AU - So, Cheuk Wai

PY - 2013/5/13

Y1 - 2013/5/13

N2 - The reactivity of the tin(II) 1,3-benzodi(thiophosphinoyl)methanediide complex [{μ-1,3-C6H4(PhPS)2C}Sn]2 (1) toward GaCl3, GeCl4, and ZnEt2 is described. The reaction of 1 with 1.7 equiv of GeCl4 in CH 2Cl2 at room temperature afforded [1,3-C6H 4(PhPS)2C(GeCl3)SnCl]2 (2). Treatment of 1 with 1.7 equiv of ZnEt2 in refluxing toluene afforded [{1,3-C6H4(PhPS)2CSnEt2}(μ-ZnS)] 2 (3). Compound 1 also reacted with 1.7 equiv of GaCl3 in CH2Cl2 to afford [1,3-C6H4(PhPS) 2C(Sn)(GaCl3)] (4). Compounds 2-4 have been characterized by NMR spectroscopy and X-ray crystallography.

AB - The reactivity of the tin(II) 1,3-benzodi(thiophosphinoyl)methanediide complex [{μ-1,3-C6H4(PhPS)2C}Sn]2 (1) toward GaCl3, GeCl4, and ZnEt2 is described. The reaction of 1 with 1.7 equiv of GeCl4 in CH 2Cl2 at room temperature afforded [1,3-C6H 4(PhPS)2C(GeCl3)SnCl]2 (2). Treatment of 1 with 1.7 equiv of ZnEt2 in refluxing toluene afforded [{1,3-C6H4(PhPS)2CSnEt2}(μ-ZnS)] 2 (3). Compound 1 also reacted with 1.7 equiv of GaCl3 in CH2Cl2 to afford [1,3-C6H4(PhPS) 2C(Sn)(GaCl3)] (4). Compounds 2-4 have been characterized by NMR spectroscopy and X-ray crystallography.

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U2 - 10.1021/om400141j

DO - 10.1021/om400141j

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SN - 0276-7333

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EP - 2648

JO - Organometallics

JF - Organometallics

IS - 9

ER -

Reactivity of a tin(II) 1,3-benzodi(thiophosphinoyl)methanediide complex toward gallium, germanium, and zinc compounds

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