Reactivity of a tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide complex toward isocyanates and rhodium(I) chloride

Jia Yi Guo; Yongxin Li; Rakesh Ganguly; Cheuk Wai So

doi:10.1021/om300062n

Reactivity of a tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide complex toward isocyanates and rhodium(I) chloride

Jia Yi Guo, Yongxin Li, Rakesh Ganguly, Cheuk Wai So^*

^*Corresponding author for this work

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

The reaction of the tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide [(PPh ₂=NSiMe ₃)(PPh ₂=S)CSn:] ₂ (1) with AdNCO (Ad = adamantyl), ArNCO (Ar = 2,6-Pr ⁱ ₂C ₆H ₃), and [RhCl(cod)] ₂ in THF afforded [(PPh ₂=NSiMe ₃)(PPh ₂=S)C{C(O)N(Ad)}Sn:] (2), [(PPh ₂=NSiMe ₃)(PPh ₂=S)C{C(O)N(Ar)}Sn ⁺:] (3), and [(PPh ₂=NSiMe ₃)(PPh ₂=S)C{Rh(cod)}(SnCl)] (4), respectively. Compounds 2-4 have been characterized by NMR spectroscopy and X-ray crystallography.

Original language	English
Pages (from-to)	3888-3893
Number of pages	6
Journal	Organometallics
Volume	31
Issue number	10
DOIs	https://doi.org/10.1021/om300062n
Publication status	Published - May 28 2012
Externally published	Yes

ASJC Scopus Subject Areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "Reactivity of a tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide complex toward isocyanates and rhodium(I) chloride",

abstract = "The reaction of the tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide [(PPh 2=NSiMe 3)(PPh 2=S)CSn:] 2 (1) with AdNCO (Ad = adamantyl), ArNCO (Ar = 2,6-Pr i 2C 6H 3), and [RhCl(cod)] 2 in THF afforded [(PPh 2=NSiMe 3)(PPh 2=S)C{C(O)N(Ad)}Sn:] (2), [(PPh 2=NSiMe 3)(PPh 2=S)C{C(O)N(Ar)}Sn +:] (3), and [(PPh 2=NSiMe 3)(PPh 2=S)C{Rh(cod)}(SnCl)] (4), respectively. Compounds 2-4 have been characterized by NMR spectroscopy and X-ray crystallography.",

author = "Guo, {Jia Yi} and Yongxin Li and Rakesh Ganguly and So, {Cheuk Wai}",

year = "2012",

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doi = "10.1021/om300062n",

language = "English",

volume = "31",

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journal = "Organometallics",

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T1 - Reactivity of a tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide complex toward isocyanates and rhodium(I) chloride

AU - Guo, Jia Yi

AU - Li, Yongxin

AU - Ganguly, Rakesh

AU - So, Cheuk Wai

PY - 2012/5/28

Y1 - 2012/5/28

N2 - The reaction of the tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide [(PPh 2=NSiMe 3)(PPh 2=S)CSn:] 2 (1) with AdNCO (Ad = adamantyl), ArNCO (Ar = 2,6-Pr i 2C 6H 3), and [RhCl(cod)] 2 in THF afforded [(PPh 2=NSiMe 3)(PPh 2=S)C{C(O)N(Ad)}Sn:] (2), [(PPh 2=NSiMe 3)(PPh 2=S)C{C(O)N(Ar)}Sn +:] (3), and [(PPh 2=NSiMe 3)(PPh 2=S)C{Rh(cod)}(SnCl)] (4), respectively. Compounds 2-4 have been characterized by NMR spectroscopy and X-ray crystallography.

AB - The reaction of the tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide [(PPh 2=NSiMe 3)(PPh 2=S)CSn:] 2 (1) with AdNCO (Ad = adamantyl), ArNCO (Ar = 2,6-Pr i 2C 6H 3), and [RhCl(cod)] 2 in THF afforded [(PPh 2=NSiMe 3)(PPh 2=S)C{C(O)N(Ad)}Sn:] (2), [(PPh 2=NSiMe 3)(PPh 2=S)C{C(O)N(Ar)}Sn +:] (3), and [(PPh 2=NSiMe 3)(PPh 2=S)C{Rh(cod)}(SnCl)] (4), respectively. Compounds 2-4 have been characterized by NMR spectroscopy and X-ray crystallography.

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Reactivity of a tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide complex toward isocyanates and rhodium(I) chloride

Abstract

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