Reversible CO2 activation by a

Jun Fan; Shina Quek; Ming Chung Yang; Zheng Feng Zhang; Ming Der Su; Cheuk Wai So

doi:10.1039/d1cc05391d

Reversible CO₂ activation by a

Jun Fan, Shina Quek, Ming Chung Yang, Zheng Feng Zhang, Ming Der Su^*, Cheuk Wai So^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

The N-phosphinoamidinato digermynes [LG̈e–G̈eL] (L = tBu₂PNC(Ph)NAr, 4: Ar = 2,6-iPr₂C₆H₃, 5: Ar = Ph) underwent reversible CO₂ activation to form [LG̈eOC(O)G̈eL] (6: Ar = 2,6-iPr₂C₆H₃, 7: Ar = Ph). Compound 7 was further reacted with diphenylacetylene and hexafluorobenzene, which proceeded through compound 5 in the first step, to form CO₂, [LG̈eC(Ph) = C(Ph) G̈eL] (8), [LG̈eF] (9) and [LG̈eC₆F₅] (10), respectively.

Original language	English
Pages (from-to)	1033-1036
Number of pages	4
Journal	Chemical Communications
Volume	58
Issue number	7
DOIs	https://doi.org/10.1039/d1cc05391d
Publication status	Published - Jan 21 2022
Externally published	Yes

Bibliographical note

Publisher Copyright:
This journal is © The Royal Society of Chemistry

ASJC Scopus Subject Areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/d1cc05391d

Cite this

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title = "Reversible CO2 activation by a",

abstract = "The N-phosphinoamidinato digermynes [L{\"G}e–{\"G}eL] (L = tBu2PNC(Ph)NAr, 4: Ar = 2,6-iPr2C6H3, 5: Ar = Ph) underwent reversible CO2 activation to form [L{\"G}eOC(O){\"G}eL] (6: Ar = 2,6-iPr2C6H3, 7: Ar = Ph). Compound 7 was further reacted with diphenylacetylene and hexafluorobenzene, which proceeded through compound 5 in the first step, to form CO2, [L{\"G}eC(Ph) = C(Ph) {\"G}eL] (8), [L{\"G}eF] (9) and [L{\"G}eC6F5] (10), respectively.",

author = "Jun Fan and Shina Quek and Yang, {Ming Chung} and Zhang, {Zheng Feng} and Su, {Ming Der} and So, {Cheuk Wai}",

note = "Publisher Copyright: This journal is {\textcopyright} The Royal Society of Chemistry",

year = "2022",

month = jan,

day = "21",

doi = "10.1039/d1cc05391d",

language = "English",

volume = "58",

pages = "1033--1036",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - Reversible CO2 activation by a

AU - Fan, Jun

AU - Quek, Shina

AU - Yang, Ming Chung

AU - Zhang, Zheng Feng

AU - Su, Ming Der

AU - So, Cheuk Wai

PY - 2022/1/21

Y1 - 2022/1/21

N2 - The N-phosphinoamidinato digermynes [LG̈e–G̈eL] (L = tBu2PNC(Ph)NAr, 4: Ar = 2,6-iPr2C6H3, 5: Ar = Ph) underwent reversible CO2 activation to form [LG̈eOC(O)G̈eL] (6: Ar = 2,6-iPr2C6H3, 7: Ar = Ph). Compound 7 was further reacted with diphenylacetylene and hexafluorobenzene, which proceeded through compound 5 in the first step, to form CO2, [LG̈eC(Ph) = C(Ph) G̈eL] (8), [LG̈eF] (9) and [LG̈eC6F5] (10), respectively.

AB - The N-phosphinoamidinato digermynes [LG̈e–G̈eL] (L = tBu2PNC(Ph)NAr, 4: Ar = 2,6-iPr2C6H3, 5: Ar = Ph) underwent reversible CO2 activation to form [LG̈eOC(O)G̈eL] (6: Ar = 2,6-iPr2C6H3, 7: Ar = Ph). Compound 7 was further reacted with diphenylacetylene and hexafluorobenzene, which proceeded through compound 5 in the first step, to form CO2, [LG̈eC(Ph) = C(Ph) G̈eL] (8), [LG̈eF] (9) and [LG̈eC6F5] (10), respectively.

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