Synthesis and characterization of a 2,6-diiminophenylgermanium(II) hydroxide, azide, and triazaphospole

Siew Peng Chia; Yongxin Li; Cheuk Wai So

doi:10.1021/om400411s

Synthesis and characterization of a 2,6-diiminophenylgermanium(II) hydroxide, azide, and triazaphospole

Siew Peng Chia, Yongxin Li, Cheuk Wai So^*

^*Corresponding author for this work

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

The reaction of the 2,6-diiminophenylgermanium(II) chloride [LGeCl] (1; L = 2,6-(HC=NAr)₂C₆H₃, Ar = 2,6-Pr ⁱ₂C₆H₃) with Me₃SnOH and NaN₃ in THF afforded [LGeOH(SnMe₃Cl)] (2) and [LGeN ₃] (3), respectively. Compound 3 underwent an uncatalyzed 1,3-dipolar cycloaddition reaction with 1-adamantylphosphaalkyne to afford the 2,6-diiminophenylgermanium(II) triazaphosphole [LGe{N₃C(Ad)P}] (4).

Original language	English
Pages (from-to)	5231-5234
Number of pages	4
Journal	Organometallics
Volume	32
Issue number	18
DOIs	https://doi.org/10.1021/om400411s
Publication status	Published - Sept 23 2013
Externally published	Yes

ASJC Scopus Subject Areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "Synthesis and characterization of a 2,6-diiminophenylgermanium(II) hydroxide, azide, and triazaphospole",

abstract = "The reaction of the 2,6-diiminophenylgermanium(II) chloride [LGeCl] (1; L = 2,6-(HC=NAr)2C6H3, Ar = 2,6-Pr i2C6H3) with Me3SnOH and NaN3 in THF afforded [LGeOH(SnMe3Cl)] (2) and [LGeN 3] (3), respectively. Compound 3 underwent an uncatalyzed 1,3-dipolar cycloaddition reaction with 1-adamantylphosphaalkyne to afford the 2,6-diiminophenylgermanium(II) triazaphosphole [LGe{N3C(Ad)P}] (4).",

author = "Chia, {Siew Peng} and Yongxin Li and So, {Cheuk Wai}",

year = "2013",

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doi = "10.1021/om400411s",

language = "English",

volume = "32",

pages = "5231--5234",

journal = "Organometallics",

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publisher = "American Chemical Society",

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T1 - Synthesis and characterization of a 2,6-diiminophenylgermanium(II) hydroxide, azide, and triazaphospole

AU - Chia, Siew Peng

AU - Li, Yongxin

AU - So, Cheuk Wai

PY - 2013/9/23

Y1 - 2013/9/23

N2 - The reaction of the 2,6-diiminophenylgermanium(II) chloride [LGeCl] (1; L = 2,6-(HC=NAr)2C6H3, Ar = 2,6-Pr i2C6H3) with Me3SnOH and NaN3 in THF afforded [LGeOH(SnMe3Cl)] (2) and [LGeN 3] (3), respectively. Compound 3 underwent an uncatalyzed 1,3-dipolar cycloaddition reaction with 1-adamantylphosphaalkyne to afford the 2,6-diiminophenylgermanium(II) triazaphosphole [LGe{N3C(Ad)P}] (4).

AB - The reaction of the 2,6-diiminophenylgermanium(II) chloride [LGeCl] (1; L = 2,6-(HC=NAr)2C6H3, Ar = 2,6-Pr i2C6H3) with Me3SnOH and NaN3 in THF afforded [LGeOH(SnMe3Cl)] (2) and [LGeN 3] (3), respectively. Compound 3 underwent an uncatalyzed 1,3-dipolar cycloaddition reaction with 1-adamantylphosphaalkyne to afford the 2,6-diiminophenylgermanium(II) triazaphosphole [LGe{N3C(Ad)P}] (4).

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DO - 10.1021/om400411s

M3 - Article

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JF - Organometallics

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ER -

Synthesis and characterization of a 2,6-diiminophenylgermanium(II) hydroxide, azide, and triazaphospole

Abstract

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