Synthesis and characterization of a germanium bismethanediide complex

Cechao Foo; Kai Chung Lau; Yi Fan Yang; Cheuk Wai So

doi:10.1039/b911384c

Synthesis and characterization of a germanium bismethanediide complex

Cechao Foo, Kai Chung Lau, Yi Fan Yang, Cheuk Wai So^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

The reaction of [(PPh₂=S)₂CH₂] (1) with MeLi followed by a salt elimination reaction with GeCl₄ in toluene afforded a novel germanium bismethanediide complex, 2. The structure of compound 2 has been determined by X-ray crystallography. The topological analysis of the electron densities of compound 2 was performed.

Original language	English
Pages (from-to)	6816-6818
Number of pages	3
Journal	Chemical Communications
Issue number	44
DOIs	https://doi.org/10.1039/b911384c
Publication status	Published - 2009
Externally published	Yes

ASJC Scopus Subject Areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/b911384c

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title = "Synthesis and characterization of a germanium bismethanediide complex",

abstract = "The reaction of [(PPh2=S)2CH2] (1) with MeLi followed by a salt elimination reaction with GeCl4 in toluene afforded a novel germanium bismethanediide complex, 2. The structure of compound 2 has been determined by X-ray crystallography. The topological analysis of the electron densities of compound 2 was performed.",

author = "Cechao Foo and Lau, {Kai Chung} and Yang, {Yi Fan} and So, {Cheuk Wai}",

year = "2009",

doi = "10.1039/b911384c",

language = "English",

pages = "6816--6818",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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AU - Foo, Cechao

AU - Lau, Kai Chung

AU - Yang, Yi Fan

AU - So, Cheuk Wai

PY - 2009

Y1 - 2009

N2 - The reaction of [(PPh2=S)2CH2] (1) with MeLi followed by a salt elimination reaction with GeCl4 in toluene afforded a novel germanium bismethanediide complex, 2. The structure of compound 2 has been determined by X-ray crystallography. The topological analysis of the electron densities of compound 2 was performed.

AB - The reaction of [(PPh2=S)2CH2] (1) with MeLi followed by a salt elimination reaction with GeCl4 in toluene afforded a novel germanium bismethanediide complex, 2. The structure of compound 2 has been determined by X-ray crystallography. The topological analysis of the electron densities of compound 2 was performed.

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DO - 10.1039/b911384c

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JO - Chemical Communications

JF - Chemical Communications

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ER -

Synthesis and characterization of a germanium bismethanediide complex

Abstract

ASJC Scopus Subject Areas

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