Synthesis and characterization of a tin(II) bis(phosphinoyl)methanediide complex: A stannavinylidene derivative

Jiayi Guo; Kai Chung Lau; Hong Wei Xi; Kok Hwa Lim; Cheuk Wai So

doi:10.1039/b922377k

Synthesis and characterization of a tin(II) bis(phosphinoyl)methanediide complex: A stannavinylidene derivative

Jiayi Guo, Kai Chung Lau, Hong Wei Xi, Kok Hwa Lim, Cheuk Wai So^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

The reaction of [CH₂(PPh₂=NSiMe₃)(PPh ₂=S)] (1) with two equivalents of [Sn{N(SiMe₃) ₂}₂] in refluxing toluene afforded novel tin(II) bis(phosphinoyl)methanediide complex 3. The structure of compound 3 has been determined by X-ray crystallography and DFT calculations. The topological analysis of the electron densities of compound 3 was performed.

Original language	English
Pages (from-to)	1929-1931
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	11
DOIs	https://doi.org/10.1039/b922377k
Publication status	Published - 2010
Externally published	Yes

ASJC Scopus Subject Areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/b922377k

Cite this

@article{304e2c60edc44f65906042286dd25a68,

title = "Synthesis and characterization of a tin(II) bis(phosphinoyl)methanediide complex: A stannavinylidene derivative",

abstract = "The reaction of [CH2(PPh2=NSiMe3)(PPh 2=S)] (1) with two equivalents of [Sn{N(SiMe3) 2}2] in refluxing toluene afforded novel tin(II) bis(phosphinoyl)methanediide complex 3. The structure of compound 3 has been determined by X-ray crystallography and DFT calculations. The topological analysis of the electron densities of compound 3 was performed.",

author = "Jiayi Guo and Lau, {Kai Chung} and Xi, {Hong Wei} and Lim, {Kok Hwa} and So, {Cheuk Wai}",

year = "2010",

doi = "10.1039/b922377k",

language = "English",

volume = "46",

pages = "1929--1931",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "11",

}

TY - JOUR

T1 - Synthesis and characterization of a tin(II) bis(phosphinoyl)methanediide complex

T2 - A stannavinylidene derivative

AU - Guo, Jiayi

AU - Lau, Kai Chung

AU - Xi, Hong Wei

AU - Lim, Kok Hwa

AU - So, Cheuk Wai

PY - 2010

Y1 - 2010

N2 - The reaction of [CH2(PPh2=NSiMe3)(PPh 2=S)] (1) with two equivalents of [Sn{N(SiMe3) 2}2] in refluxing toluene afforded novel tin(II) bis(phosphinoyl)methanediide complex 3. The structure of compound 3 has been determined by X-ray crystallography and DFT calculations. The topological analysis of the electron densities of compound 3 was performed.

AB - The reaction of [CH2(PPh2=NSiMe3)(PPh 2=S)] (1) with two equivalents of [Sn{N(SiMe3) 2}2] in refluxing toluene afforded novel tin(II) bis(phosphinoyl)methanediide complex 3. The structure of compound 3 has been determined by X-ray crystallography and DFT calculations. The topological analysis of the electron densities of compound 3 was performed.

UR - http://www.scopus.com/inward/record.url?scp=77949416417&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=77949416417&partnerID=8YFLogxK

U2 - 10.1039/b922377k

DO - 10.1039/b922377k

M3 - Article

C2 - 20198256

AN - SCOPUS:77949416417

SN - 1359-7345

VL - 46

SP - 1929

EP - 1931

JO - Chemical Communications

JF - Chemical Communications

IS - 11

ER -

Synthesis and characterization of a tin(II) bis(phosphinoyl)methanediide complex: A stannavinylidene derivative

Abstract

ASJC Scopus Subject Areas

Access to Document

Other files and links

Fingerprint

Cite this