Synthesis of chalcogeno[3-(pyrid-2-yl)-1-azaallyl]germanium complexes

Wing Por Leung; Kim Hung Chong; Yuen Sze Wu; Cheuk Wai So; Hoi Shan Chan; Thomas C.W. Mak

doi:10.1002/ejic.200500717

Synthesis of chalcogeno[3-(pyrid-2-yl)-1-azaallyl]germanium complexes

Wing Por Leung^*, Kim Hung Chong, Yuen Sze Wu, Cheuk Wai So, Hoi Shan Chan, Thomas C.W. Mak

^*Corresponding author for this work

Chinese University of Hong Kong

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

The reaction of [Ge{C(C₅H₄N-2)C(Ph)N(SiMe ₃)₂}{N(SiMe₃)C(Ph)C(SiMe₃)(C ₅H₄N-2)}] (1) and [Ge{N(SiMe₃)C(Ph)C(SiMe ₃)(C₅H₄N-2)}Cl] (2) with stoichiometric amounts of elemental chalcogens in toluene affords [Ge(E){C(C₅H ₄N-2)C(Ph)N(SiMe₃)₂}{N(SiMe₃)C(Ph) C(SiMe₃)(C₅H₄N-2)}] [E = S (3), Se (4)] and [Ge(E){N(SiMe₃)C(Ph)C(SiMe₃)(C₅H ₄N-2)}Cl] [E = S (5), Se (6)], respectively. Compounds 3-6 were characterized by X-ray analysis.

Original language	English
Pages (from-to)	808-812
Number of pages	5
Journal	European Journal of Inorganic Chemistry
Issue number	4
DOIs	https://doi.org/10.1002/ejic.200500717
Publication status	Published - Feb 20 2006
Externally published	Yes

ASJC Scopus Subject Areas

Inorganic Chemistry

Keywords

Chalcogens
Germanium
N ligands

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10.1002/ejic.200500717

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@article{52043f00f7b94a69a10163e6fe765b29,

title = "Synthesis of chalcogeno[3-(pyrid-2-yl)-1-azaallyl]germanium complexes",

abstract = "The reaction of [Ge\{C(C5H4N-2)C(Ph)N(SiMe 3)2\}\{N(SiMe3)C(Ph)C(SiMe3)(C 5H4N-2)\}] (1) and [Ge\{N(SiMe3)C(Ph)C(SiMe 3)(C5H4N-2)\}Cl] (2) with stoichiometric amounts of elemental chalcogens in toluene affords [Ge(E)\{C(C5H 4N-2)C(Ph)N(SiMe3)2\}\{N(SiMe3)C(Ph) C(SiMe3)(C5H4N-2)\}] [E = S (3), Se (4)] and [Ge(E)\{N(SiMe3)C(Ph)C(SiMe3)(C5H 4N-2)\}Cl] [E = S (5), Se (6)], respectively. Compounds 3-6 were characterized by X-ray analysis.",

keywords = "Chalcogens, Germanium, N ligands",

author = "Leung, \{Wing Por\} and Chong, \{Kim Hung\} and Wu, \{Yuen Sze\} and So, \{Cheuk Wai\} and Chan, \{Hoi Shan\} and Mak, \{Thomas C.W.\}",

year = "2006",

month = feb,

day = "20",

doi = "10.1002/ejic.200500717",

language = "English",

pages = "808--812",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "John Wiley and Sons Ltd",

number = "4",

}

TY - JOUR

T1 - Synthesis of chalcogeno[3-(pyrid-2-yl)-1-azaallyl]germanium complexes

AU - Leung, Wing Por

AU - Chong, Kim Hung

AU - Wu, Yuen Sze

AU - So, Cheuk Wai

AU - Chan, Hoi Shan

AU - Mak, Thomas C.W.

PY - 2006/2/20

Y1 - 2006/2/20

N2 - The reaction of [Ge{C(C5H4N-2)C(Ph)N(SiMe 3)2}{N(SiMe3)C(Ph)C(SiMe3)(C 5H4N-2)}] (1) and [Ge{N(SiMe3)C(Ph)C(SiMe 3)(C5H4N-2)}Cl] (2) with stoichiometric amounts of elemental chalcogens in toluene affords [Ge(E){C(C5H 4N-2)C(Ph)N(SiMe3)2}{N(SiMe3)C(Ph) C(SiMe3)(C5H4N-2)}] [E = S (3), Se (4)] and [Ge(E){N(SiMe3)C(Ph)C(SiMe3)(C5H 4N-2)}Cl] [E = S (5), Se (6)], respectively. Compounds 3-6 were characterized by X-ray analysis.

AB - The reaction of [Ge{C(C5H4N-2)C(Ph)N(SiMe 3)2}{N(SiMe3)C(Ph)C(SiMe3)(C 5H4N-2)}] (1) and [Ge{N(SiMe3)C(Ph)C(SiMe 3)(C5H4N-2)}Cl] (2) with stoichiometric amounts of elemental chalcogens in toluene affords [Ge(E){C(C5H 4N-2)C(Ph)N(SiMe3)2}{N(SiMe3)C(Ph) C(SiMe3)(C5H4N-2)}] [E = S (3), Se (4)] and [Ge(E){N(SiMe3)C(Ph)C(SiMe3)(C5H 4N-2)}Cl] [E = S (5), Se (6)], respectively. Compounds 3-6 were characterized by X-ray analysis.

KW - Chalcogens

KW - Germanium

KW - N ligands

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U2 - 10.1002/ejic.200500717

DO - 10.1002/ejic.200500717

M3 - Article

AN - SCOPUS:33644617990

SN - 1434-1948

SP - 808

EP - 812

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 4

ER -

Synthesis of chalcogeno[3-(pyrid-2-yl)-1-azaallyl]germanium complexes

Abstract

ASJC Scopus Subject Areas

Keywords

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